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Assessment of the aroma impact of major odor-active thiols in pan-roasted white sesame seeds by calculation of odor activity values
Authors:Tamura Hitoshi  Fujita Akira  Steinhaus Martin  Takahisa Eisuke  Watanabe Hiroyuki  Schieberle Peter
Institution:Technical Research Institute, R&D Center, T. Hasegawa Company, Ltd., 29-7, Kariyado, Nakahara-ku, Kawasaki-shi 211-0022, Japan. hitoshi_tamura@t-hasegawa.co.jp
Abstract:Eleven odor-active thiols, namely, 2-methyl-1-propene-1-thiol, (Z)-3-methyl-1-butene-1-thiol, (E)-3-methyl-1-butene-1-thiol, (Z)-2-methyl-1-butene-1-thiol, (E)-2-methyl-1-butene-1-thiol, 2-methyl-3-furanthiol, 3-mercapto-2-pentanone, 2-mercapto-3-pentanone, 4-mercapto-3-hexanone, 3-mercapto-3-methylbutyl formate, and 2-methyl-3-thiophenethiol, recently identified in an extract prepared from white sesame seeds, were quantitated in sesame using stable isotope dilution analyses. For that purpose, the following deuterium-labeled compounds were synthesized and used as internal standards in the quantitation assays: 2H6]-2-methyl-1-propene-1-thiol, 2H3]-(E)- and 2H3]-(Z)-2-methyl-1-butene-1-thiol, 2H3]-2-methyl-3-furanthiol, 2H2]-3-mercapto-2-pentanone, 2H3]-4-mercapto-3-hexanone, 2H6]-3-mercapto-3-methylbutyl formate, and 2H3]-2-methyl-3-thiophenethiol. On the basis of the results obtained, odor activity values (OAVs) were calculated as ratio of the concentration and odor threshold of the individual compounds in cooking oil. According to their high OAVs, particularly the 3-methyl-1-butene-1-thiols (OAV: 2400) and the 2-methyl-1-butene-1-thiols (OAV: 960) were identified as the most odor-active compounds in pan-roasted white sesame seeds. These compounds were therefore suggested to be mainly responsible for the characteristic but rather unstable sulfury aroma of freshly pan-roasted white sesame seeds.
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