Synthesis and characterization of boron doped alumina stabilized zirconia fibers |
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Authors: | ? Uslu T Tunç S Keskin M K Öztürk |
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Institution: | (1) Faculty of Education, Department of Science, Aksaray University, 68100 Aksaray, Turkey;(2) Gazi Faculty of Education, Department of Chemistry Education Beseveler, Gazi University, 06500 Ankara, Turkey;(3) Institute of Natural and Applied Sciences, Department of Mechanical Engineering, Selcuk University, 42090 Konya, Turkey;(4) Central Laboratory, Middle East Technical University, Eskişehir Highway, 06531 Ankara, Turkey;(5) Faculty of Engineering & Architecture, Department of Mechanical Engineering, Selcuk University, 42090 Konya, Turkey |
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Abstract: | Boron doped PVA/Zr-Al acetate nanofibers were prepared by electrospinning using PVA as a precursor. The effect of calcination
temperature on morphology and crystal structure was investigated at 250, 500, and 800 °C. The study also establishes the effect
of boron doping on the morphology of PVA/Zr-Al acetate nanofibers at various calcination temperatures. The measurements showed
that the conductivity, pH, viscosity and the surface tension of the hybrid polymer solutions have increased with boron doping.
In addition, the fibers were characterized by FTIR, DSC, XPS, XRD and SEM techniques. The addition of boron did not only increase
the thermal stability of the fibers, but also increased the average fiber diameters, which gave stronger fibers. The DSC results
indicated that the melting temperature (Tm) of the fibers was increased from 256 to 270 °C with the addition of boron. XRD
peak patterns showed that after further heat treatment at 800 °C, zirconia exists in two phases of tetragonal and monoclinic
modifications. Moreover, alumina does not transform into the γ-Al2O3 and θ-Al2O3 phase at 800 °C. The SEM appearance of the fibers showed that the addition of boron resulted in the formation of crosslinked
bright surfaced fibers. |
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