| 十六烷基三甲基铵C60盐的合成和性质 |
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| 引用本文： | 张辉 杜俊 等. 十六烷基三甲基铵C60盐的合成和性质[J]. 安徽农业大学学报, 2002, 29(2): 196-198. DOI: 10.3969/j.issn.1672-352X.2002.02.023 |
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| 作者姓名： | 张辉 杜俊 等 |
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| 作者单位： | 1. 黄山高等专科学校化学系,黄山,245000;2. 安徽师范大学化学与材料科学学院 |
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| 基金项目： | 安徽省自然科学基金;45122; |
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| 摘 要： | 采用钠萘作还原剂制备C60负一价离子,计量易控制,方法简便.利用复分解反应首次合成了十六烷基三甲基铵的C60盐,产物经UV-NIR、IR、ESI-MS表征,并研究了其ESR性质和被空气氧化的过程.
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| 关 键 词： | C60负离子 十六烷基三甲基铵 合成 氧化 |
| 文章编号： | 1000-2197(2002)02-0196-03 |
| 修稿时间： | 2001-09-29 |
Synthesis and Properties of Hexadecyl Trimethyl Ammonium Buckminsterfulleride |
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| ZHANG Hui,DU Jun,LU Xiao jing,WEI Xian wen. Synthesis and Properties of Hexadecyl Trimethyl Ammonium Buckminsterfulleride[J]. Journal of Anhui Agricultural University, 2002, 29(2): 196-198. DOI: 10.3969/j.issn.1672-352X.2002.02.023 |
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| Authors: | ZHANG Hui DU Jun LU Xiao jing WEI Xian wen |
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| Affiliation: | ZHANG Hui 1,DU Jun 2,LU Xiao jing 2,WEI Xian wen 2 |
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| Abstract: | C - 60 anion was obtained by using potassium naphthalide as a reductant, which is a facile method and easy to control the stoichiometry of reductant. Hexadecyl trimetnyl ammonium buckminsterfulleride was first synthesized by metathetical reaction. The product was characterized by UV NIR, IR, ESI MS, its ESR and the oxidation reaction were also studied |
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| Keywords: | buckminsterfulleride hexadecyl trimethyl ammonium synthesis oxidation |
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