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通风条件对ACQ-D处理杉木中铜固着的加速作用
引用本文:于丽丽,郭宁,曹金珍. 通风条件对ACQ-D处理杉木中铜固着的加速作用[J]. 北京林业大学学报, 2008, 30(5): 123-128
作者姓名:于丽丽  郭宁  曹金珍
作者单位:北京林业大学材料科学与技术学院
基金项目:霍英东教育基金会第十届高等院校青年教师基金(优选资助课题),全国高等学校优秀博士学位论文作者专项基金
摘    要:为了研究在不同相对湿度的热空气后处理过程中,通风条件对胺溶铜季铵盐 D型(ACQ-D)处理杉木中有效成分铜固着的影响,该实验在30%、50%、80% 3个相对湿度条件下,将ACQ-D处理过的杉木置于通风和不通风条件下分别进行热空气处理,然后按照AWPA E11-97流失实验标准进行铜的抗水流失实验,实验结束后,利用原子吸收分光光度计测定试材中残留的铜含量,并计算ACQ-D处理杉木中铜的流失率。结果表明:① 通风条件对铜在木材中的抗流失性影响显著,除相对湿度30%、处理时间为4 h组试件外,通风组试件中铜的流失率均较不通风组有明显降低;② 热空气后处理过程中较高的相对湿度,有利于加速通风条件下ACQ-D处理杉木中铜的固着速率,可迅速提高铜的抗流失性,但对不通风组试件影响不大。 

关 键 词:杉木   胺溶铜季铵盐-D型     抗流失性   通风条件
收稿时间:1900-01-01

Effects of circulation condition on copper leaching resistance in ACQ-D treated Chinese fir
YU Li-li,GUO Ning,CAO Jin-zhen.College of Material Science , Technology,Beijing Forestry University,,P.R.China. Effects of circulation condition on copper leaching resistance in ACQ-D treated Chinese fir[J]. Journal of Beijing Forestry University, 2008, 30(5): 123-128
Authors:YU Li-li  GUO Ning  CAO Jin-zhen.College of Material Science    Technology  Beijing Forestry University    P.R.China
Affiliation:College of Material Science and Technology, Beijing Forestry University, 100083,P. R. China
Abstract:In order to clarify the effect of circulation condition on the fixation process of copper with different relative humidity conditions during hot air post-treatment, Chinese fir (Cunninghamia lanceolata Hook) treated by amine copper quat-type D (ACQ-D) was post-treated in three different relative humidity conditions(30%, 50% and 80%) with or without ventilation. After post-treatment, leaching tests were carried out according to AWPA E11-97 and the percentage of copper leached out from the samples was calculated based on the copper amount remained in the samples after leaching tests, which was determined by atomic absorption spectroscopy (AAS). The results show that: 1) Circulation has a significant effect on copper leaching resistance in ACQ-D treated Chinese fir. The percentage of copper leached out in circulation groups decreased more significantly than in non circulation groups, except the group in 30% relative humidity for 4 hours during hot air post treatment. 2) Higher relative humidity accelerates the copper fixation rates in circulation groups during hot air post-treatment and improves the copper leaching resistance in a short time. For the non-circulation groups, the effect of relative humidity is negligible.
Keywords:Cunninghamia lanceolata Hook  amine copper quat-type D  copper  leaching resistance  circulation condition  
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