| 棉秆催化热解的TG-MS分析 |
| |
| 引用本文： | 吕博,刘建国,杨鲁斌,姜秀民.棉秆催化热解的TG-MS分析[J].安徽农业科学,2013(26):10785-10787. |
| |
| 作者姓名： | 吕博 刘建国 杨鲁斌 姜秀民 |
| |
| 作者单位： | 上海交通大学机械与动力工程学院;热能工程研究所; |
| |
| 基金项目： | 国家自然科学基金(50906051) |
| |
| 摘 要： | 目的]利用热重-质谱联用（TG-MS）技术,分析了棉秆在催化条件下的热解过程.方法]采用活化热解区与消极热解区法、热解特性指数法,比较了CaO、MgO对棉秆热解的影响,通过质谱分析研究了CaO、MgO对棉秆热解过程中焦油组分析出的影响.结果]CaO、MgO对棉秆的活化区和消极区均有催化作用,且CaO、MgO对棉秆的挥发分析出特性具有改善作用;棉秆热解产生的焦油组分主要为苯、甲苯、苯酚,CaO、MgO的加入使焦油组分的析出温度范围变窄、离子强度下降.结论]该研究为棉杆的催化热解研究提供了科学参考.
|
| 关 键 词： | 生物质 催化热解 热重分析 质谱分析 |
Catalytic Pyrolysis of Cotton Stalk with TG-MS Analyzer |
| |
| Institution: | LV Bo(Institute of Thermal Energy Engineering, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240) |
| |
| Abstract: | Objective] Catalytic pyrolysis characteristics of cotton stalk were studied with TG-MS analyzer.Method] By using the active and passive zone as well as pyrolysis index,the influences of CaO and MgO on the pyrolysis characteristics and the tar evolution during the heating processes were discussed.Result] CoO and MgO had catalytic effects on both the active and passive pyrolysis zone of cotton stalk; CaO and MgO promoted the precipitation of the volatiles ; the mass spectrometry analysis showed that the main components of tar were benzene,toluene and phenol; CaO and MgO narrowed the temperature range of the tar precipitation and reduced the peak values of the tar components.Conclusion] The research could provide scientific references for the catalytic pyrolysis of cotton stalk in future. |
| |
| Keywords: | Biomass Catalytic pyrolysis Thermogravimetric analysis Mass spectrometry analysis |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
