| 保护风蚀地的刺山柑 |
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| 引用本文： | 何江波, 欧阳芬, 张燊, 等. 刺山柑化学成分研究[J]. 云南农业大学学报（自然科学）, 2018, 33(3): 558-562. DOI: 10.12101/j.issn.1004-390X(n).201704015 |
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| 作者姓名： | 何江波 欧阳芬 张燊 王波 句红萍 陶剑 张雪梅 芮丹云 牛燕芬 |
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| 作者单位： | 1.昆明学院，昆明市呼吸系统疾病防治重点实验室，云南 昆明 650214;2.昆明市艺术学校，云南 昆明 650216;3.昆明学院 农学院，云南 昆明 650214 |
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| 基金项目： | 云南省科技厅青年基金项目（2016FD109）；云南省教育厅资助项目（2017ZZX091） |
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| 摘 要： | ttttt目的ttttt研究刺山柑(Capparis spinosa L.)的化学成分。tttttttttttttttttt方法ttttt运用硅胶柱色谱、凝胶柱色谱(Sephadex LH-20)和反相RP-18柱色谱对乙酸乙酯部位进行分离纯化，然后通过现代波谱学鉴定方法(1H-NMR，13C-NMR，MS)，结合文献数据分析确定化合物的结构。tttttttttttttttttt结果ttttt从刺山柑乙酸乙酯部位分离得到12个化合物，依次确定为(R)-2-甲基-2,4-二甲氧基-6H-吡喃-3-酮(1)，1H-吲哚-3-乙腈-4-O-β-吡喃型葡萄糖苷(2)，3-吲哚甲酸(3)，尿嘧啶(4)，5-(methoxymethyl)-1H-pyrrole-2-carbaldehyde(5)，4-羟基-5-甲基呋喃-3-羧酸(6)，苯甲酸(7)，水杨酸(8)，(2R,4aR,8aR)-3,4,4a,8a-tetrahydro-4a-hydroxy-2,6,7,8a-tetramethyl-2-(4,8,12-trimethyltridecyl)-2H-chromene-5,8-dione (9)，α-生育酚(10)，异槲皮苷(11)，芸香苷(12)。tttttttttttttttttt结论ttttt化合物1，3，5，6，9，10均为首次从刺山柑中分离得到。tttt
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| 关 键 词： | 刺山柑 提取分离 化学结构 结构鉴定 |
| 收稿时间： | 2017-04-08 |
| 修稿时间： | 2017-05-12 |
1H-Indole-3 acetonitrile glycosides from Capparis spinosa fruits |
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| Jiangbo HE, Fen OUYANG, Shen ZHANG, et al. Chemical Constituents from Capparis spinosa L.[J]. JOURNAL OF YUNNAN AGRICULTURAL UNIVERSITY（Natural Science）, 2018, 33(3): 558-562. DOI: 10.12101/j.issn.1004-390X(n).201704015 |
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| Authors: | Jiangbo HE Fen OUYANG Shen ZHANG Bo WANG Hongping JU Jian TAO Xuemei ZHANG Danyun RUI Yanfen NIU |
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| Affiliation: | 1.Kunming Key Laboratory of Respiratory Disease, Kunming University, Kunming 650214, China;2.Kunming Arts School, Kunming 650216, China;3.School of Agriculture, Kunming University, Kunming 650214, China |
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| Abstract: | tttttPurposetttttThe chemical constituents of Capparis spinosa L. were analyzed.ttttttttttttttttttMethodtttttThe compounds were isolated by silica column chromatography, Sephadex LH-20 column chromatography and RP-18 reverse-phase column chromatography from the EtOAc extract. The structures were characterized by various spectroscopic (1H-NMR, 13C-NMR and MS) and comparison with the data of literatures.ttttttttttttttttttResulttttttTwelve compounds were isolated from the EtOAc extract, and identified as (R)-2,4-dimethoxy-2-methyl-6H-pyran-3-one (1), capparilosides A (2), indole-3-carboxylic acid (3), uracil (4), 5-(methoxymethyl)-1H-pyrrole-2-carbaldehyde (5), 4-hydroxy-5-methylfuran-3-carboxylic acid (6), benzoic acid (7), salicylic acid (8), (2R,4aR,8aR)-3,4,4a,8a-Tetrahydro-4a-hydroxy-2,6,7,8a-tetramethyl-2-(4,8,12-trimethyltridecyl)-2H-chromene-5,8-dione (9), α-tocopherol (10), isoquercitrin (11), rutin (12).ttttttttttttttttttConclusiontttttCompounds 1, 3, 5, 6, 9, 10 were isolated from C. spinosa L. for the first time.ttttttttt |
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| Keywords: | Capparis spinosa L. extraction and isolation chemical constituents structural identification |
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