Aluminum concentrations in sclerotia from a buried humic horizon of volcanic ash soils in Mt. Myoko,Central Japan |
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Authors: | Makiko Watanabe Nobuhide Fujitake Hiroyuki Ohta Takushi Yokoyama |
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Institution: | 1. Interdisciplinary Graduate School of Science and Engineering , Tokyo Institute of Technology , Yokohama , 226-8502 , Japan;2. Faculty of Agriculture , Kobe University , Kobe , 657-8501 , Japan;3. Ibaraki University College of Agriculture , Ami-machi, Ibaraki , 300-0393 , Japan;4. Faculty of Science , Kyushu University , Kyushu University , 812-8581 , Japan |
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Abstract: | The morphology and chemical composition of fungal sclerotium-like grains collected from the buried humic horizon of volcanic ash soil in Mt. Myoko were examined using a scanning electron microscope (SEM), energy dispersion xray micro-analyzer (EDX), and electron probe micro-analyzer (EPMA). A high C content, low level of Si and high concentration of Al characterized the grains considered to correspond to the sclerotia of Cenoccocum graniforme. The 27Al MAS NMR spectrum of the sclerotia showed the existence of 6- and 4-coordinated Al. X-ray diffraction analyses supported the presence of amorphous Al (ex. Al-humus complex) in the sclerotia. |
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Keywords: | Al concentration 27Al MAS NMR EPMA sclerotia volcanic ash soils |
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