Application of triazole-containing gemini cationic darkening agent in cold pad batch dyeing for cotton knits |
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Authors: | Cheng Chen Lixia Jia Guohua Shan Rui Liu Yuanshu Xiao Huifang Zhang Ying He |
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Institution: | 1.College of Textiles and Apparels,Xinjiang University,Urumqi,China;2.College of Textile and Clothing,Jiangnan University,Wuxi,China;3.College of Chemistry, Chemical Engineering and Biotechnology,Donghua University,Shanghai,China;4.Xinjiang Fang Ting Knitting Textile Co., Ltd.,Urumqi,China;5.Guangzhou King Eagle Biological Technology Co., Ltd.,Guangzhou,China |
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Abstract: | 4-Amino-double(octadecyldimethyl ammonium chloride)-1,2,4-triazole (ADAC-TZ), a gemini cationic auxiliary with a heterocyclic triazole structure, was designed and synthesized by the method described here and characterized for use in the cold pad batch dyeing of cotton knits. The results show that, for ADAC-TZ, the critical micelle concentration (CMC) is 4.0×10-4 mol/l, the Krafft point is 29.8 °C, the foam height is only 169 mm/5 min, and the solubilization for toluene is 6.67 ml/g, which means that ADAC-TZ exhibits excellent low-foaming, water solubility and solubilization properties. The present research also demonstrates that ADAC-TZ pretreatment can increase the K/S value, dye fixation, and color fastness to washing and rubbing of cotton knits dyed through BES reactive dye cold pad batch dyeing used in combination with the alkaline agent QF-4. |
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