Antiradical properties of red wine portisins |
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Authors: | Pirker Katharina F Oliveira Joana de Freitas Victor Goodman Bernard A Mateus Nuno |
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Affiliation: | Health and Environment Department, Environmental Resources and Technologies, AIT Austrian Institute of Technology GmbH, Konrad-Lorenz-Stra?e 24, 3430 Tulln, Austria. |
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Abstract: | The free radical chemistry of two polyphenolic pigments from red wine, belonging to the family of portisins, has been investigated after reaction with O(2)(?-) radicals using electron paramagnetic resonance (EPR) spectroscopy. Two portisins derived from malvidin-3-glucoside and cyanidin-3-glucoside were used for this study. Stable free radicals were detected with both portisins and correspond to unpaired electrons localized on the B as well as F rings of the portisins. Interpretations were confirmed by comparison with the spectra of free radicals formed by oxidation of the model compounds cyanidin-3-glucoside, malvidin-3-glucoside, and catechin. These results concur with previous work reporting the higher antiradical properties of these pigments compared to their anthocyanin precursors. |
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