| 2-氰基-3-(6-氯-3-吡啶甲基)胺基-3-脂肪胺基丙烯腈的合成与生物活性 |
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| 引用本文： | 余申义,李正名.2-氰基-3-(6-氯-3-吡啶甲基)胺基-3-脂肪胺基丙烯腈的合成与生物活性[J].农药学学报,2001,3(3):18-22. |
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| 作者姓名： | 余申义 李正名 |
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| 作者单位： | 1.北京化工大学理学院, 北京 100029 |
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| 摘 要： | 以 3-氨甲基吡啶和 2 -氯 - 5 -氨甲基吡啶为原料先与 2 -氰基 - 3,3-二甲硫基丙烯腈反应 ,产物不经分离再与脂肪胺反应合成了 14个未见文献报道的开环类吡虫啉结构类似物。所有目标化合物均经元素分析、1H NMR确证。初步活性测试结果表明含硫化合物的杀虫活性优于双氨基化合物 ,其中 4 c对豆蚜的抑制率最高达 87.6%。
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| 关 键 词： | 3-氨甲基吡啶 烯酮二硫缩醛 脂肪胺 合成 生物活性 |
Synthesis and Biological Activities of 2-Cyano-3-(6-Chloro-3-Pyridylmethyl)Amino-3-Aliphatic Amine Acrylonitrile |
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| Yu Shen-yi and Li Zheng-ming.Synthesis and Biological Activities of 2-Cyano-3-(6-Chloro-3-Pyridylmethyl)Amino-3-Aliphatic Amine Acrylonitrile[J].Chinese Journal of Pesticide Science,2001,3(3):18-22. |
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| Authors: | Yu Shen-yi and Li Zheng-ming |
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| Institution: | 1.Institute of Science2.Beijing University of Chemical Technology |
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| Abstract: | After the reaction of 3 aminomethyl or 2 chloride 5 aminomethyl pyridine with 2 cyano 3,3 dimethylthioacrylonitrile, the simple fatty amines were added to the unseparated reactant.Fourteen novel compounds were obtained. All the structures were confirmed by elemental analysis , 1H NMR and the insecticidal activities of the compounds were evaluated. |
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| Keywords: | 3-Aminomethylpyridine Ketene dithioacetals Fatty amine Synthesis Biological activity |
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