甲基丙烯酸甲酯改性白炭黑/NR复合材料的研究 |
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引用本文: | 张可喜,汪志芬,符 新,林 华.甲基丙烯酸甲酯改性白炭黑/NR复合材料的研究[J].热带作物学报,2009,29(12):9-11. |
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作者姓名: | 张可喜 汪志芬 符 新 林 华 |
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作者单位: | 海南大学材料与化工学院 海南海口 5702282;海南大学材料与化工学院 海南海口 5702282;海南大学机电工程学院 海南海口 5702282;海南大学材料与化工学院 海南海口 5702282 |
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摘 要: | 在天然胶乳(NRL)和白炭黑(WC)为主的体系中,引入适量的甲基丙烯酸甲酯单体(MMA)和引发剂,利用单体对白炭黑表面发生接枝反应的同时,实现其与橡胶大分子链通过化学键相连接,乳液共沉制备白炭黑填充型天然橡胶复合材料(NR/WC/MMA)。复合材料具有良好的加工流动性、力学性能和耐老化性能。
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关 键 词: | 甲基丙烯酸甲酯 白炭黑 天然橡胶 填充 性能 |
Preparation of White Carbon Black/NR Composite Modified with Methyl methacrylate by in-situ Grafting in Latex |
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Institution: | College of Materials and Chemical Engineering, Hainan University, Haikou, Hainan 570228;College of Materials and Chemical Engineering, Hainan University, Haikou, Hainan 570228;College of Mechanical and Electrical Engineering, Haikou, Hainan 570228;College of Materials and Chemical Engineering, Hainan University, Haikou, Hainan 570228 |
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Abstract: | Methyl methaacrylate (MMA) monomer and initiating agent were added at a proper rate into the system based on natural rubber latex and white carbon black. The monomer was grafted onto the sur-face of white black carbon and at the same time ligated with rubber macromolecule chain via chemical bonds. The natural rubber composites NR/WC/MMA filled with white carbon black were prepared by us-ing the latex co-precipitation method. This composite has a good processing fluidity, dynamic property and aging performance. |
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Keywords: | ethyl methaacrylate white carbon black (WC) natural rubber filling in properties |
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