工业副产物硒的氧化 |
| |
作者姓名: | 王金玲 刘登才 |
| |
作者单位: | 华中农业大学理学院,华中农业大学动物医学院,湖北,武汉,430070 |
| |
摘 要: | 在化学反应中,二氧化硒作为温和的氧化剂,可以将羟基、甲基等基团氧化为醛基,而本身被还原为硒,成为废弃物。以合成反应中生成的硒为原料,用浓硝酸和浓硫酸的混合物进行氧化反应,使其氧化为可以重复使用的二氧化硒,反应收率为94%,并用滴定法测定其含量为96%,符合工业化生产的要求。
|
关 键 词: | 二氧化硒 硒 氧化反应 收率 含量 |
Oxidation of By-Production Selenium in Synthesis Reaction |
| |
Authors: | Wang Jinling Liu Dengcai |
| |
Abstract: | In chemical reaction, dioxide selenium, as gentle oxidant ,can oxidized some group,such as hydroxide ,methyl to aldehyde group, and was reduced to selenium itself. Selenium produced in synthesis reaction was oxidized to recyclable dioxide selenium by the mixture of concentrated nitric acid and sulfuric acid. The reaction yield was 94%. The content of dioxide selenium produced was 96% and fit to the need of industry produce. |
| |
Keywords: | Dioxide selenium Selenium Oxidation Yield Content |
本文献已被 CNKI 维普 万方数据 等数据库收录! |
| 点击此处可从《》浏览原始摘要信息 |
| 点击此处可从《》下载免费的PDF全文 |
|