Property of nano-SiO2/urea formaldehyde resin |
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Authors: | Qiaojia Lin Guidi Yang Jinghong Liu Jiuping Rao |
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Institution: | (1) Material Engineering College, Fujian Agriculture and Forestry University, Fuzhou, 350002, China |
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Abstract: | In this paper, we discuss the effects of a nanometer silicon dioxide (nano-SiO2) coupling agent, dispersal methods and the amount of nano-SiO2/urea formaldehyde resin. The results of our study indicate that when nano-SiO2, using KH-550 silane as a coupling agent, was added to UF resin by discontinuous ultrasonic vibration, its properties improved
effectively. When the content of nano-SiO2 was below 1.5%, the amount of free formaldehyde decreased, and the viscosity and bonding strength of resin increased with
an increase in the added nano-SiO2, which did not prolong the curing time. The performance indices of plywood, particleboard and medium density fiberboard (MDF),
hot-pressed by nano-SiO2 (1%)/UF resin (F/U molar ratio=1.2), exceeded the requirements of the National Standard. Their free
formaldehyde emission reached E1 grade. Finally, we analyzed the mechanism of the strengthening effects of nano-SiO2 on UF resin by means of infrared spectrum analysis and X-ray photoelectronic spectrum (XPS).
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Translated from Scientia Silvae Sinicae, 2005, 41(2) 译自: 林业科学, 2005, 41(2)] |
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Keywords: | nanometer silicon dioxide urea formaldehyde (UF) resin bonding strength free formaldehyde X-ray photoelectronic spectrum (XPS) |
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