| 在Fe^3＋和漆酚的共同催化下过氧化氢氧化苯成苯酚 |
| |
| 引用本文： | 雷福厚,郭明高.在Fe^3＋和漆酚的共同催化下过氧化氢氧化苯成苯酚[J].林产化学与工业,1992,12(1):65-70. |
| |
| 作者姓名： | 雷福厚 郭明高 |
| |
| 作者单位： | 湖北省化学研究所 武昌430074
(雷福厚，郭明高)，湖北省化学研究所 武昌430074(喻宗源) |
| |
| 基金项目： | 湖北省自然科学基金资助项目 |
| |
| 摘 要： |
|
| 关 键 词： | 漆酚 催化 羟基化 苯酚 |
HYDROXYLATION OF BENZENE WITH HYDROGEN PEROXIDE USING URUSHIOL AND Fe~(3+) COMPLEXES AS CATALYST |
| |
| Lei Fuhou Guo Minggao Yu Zongyuan.HYDROXYLATION OF BENZENE WITH HYDROGEN PEROXIDE USING URUSHIOL AND Fe~(3+) COMPLEXES AS CATALYST[J].Chemistry & Industry of Forest Products,1992,12(1):65-70. |
| |
| Authors: | Lei Fuhou Guo Minggao Yu Zongyuan |
| |
| Abstract: | Hydroxylation of benzene with H2O2 was carried out in the presence of urushiol and Fe3+ in a benzene-water biphase system. The mixture of urushiol and Fe3+ was found to be a more effective catalyst which gave 45% yield of phenol and the yield was only 4. 4% while using Fe3+ alone. Factors influencing the yield such as temperature of reaction. concentrations of H2O2. pH of the solution and ratio of urushiol to Fe3+ were studied. And the possible mechanism of the reaction was also discussed. |
| |
| Keywords: | Urushiol Catalysis Hydroxylation Phenol |
| 本文献已被 CNKI 维普 等数据库收录！ |
