Management of N mineralization from crop residues of high N content using amendment materials of varying quality

Abstract. A potential technique for reducing overwinter leaching from high N containing crop residues is to immobilize the N released during decomposition by co-incorporating materials of a wider C : N ratio. This article describes the use of laboratory incubation experiments to investigate the effects of a wide range of such amendment materials on the mineralization of N from sugar beet and brassica leaf residues in a sandy loam and a silt loam. These materials were of varying quality, with C : N ratio ranging from 15 : 1 to 520 : 1, and cellulose content from 0 to 34%. Amendments were added at a fixed rate of 3.5 mg C g⁻¹ of dry soil, equivalent to around 10 t ha⁻¹ C (to 20 cm depth). The soils were then incubated at 15°C, and net mineral N derived from the leaves was measured at regular intervals over 168 days. Net mineralization of residue N was greatest with molasses (C : N ratio of 18 : 1), whereas paper waste (C : N ratio of 520 : 1) reduced N mineralized by up to 90% compared with a soil-only control. As the concentration of cellulose and lignin in the amendment materials increased, so the amounts of N mineralized decreased, with 62 and 54% of variance in N mineralized explained by cellulose and lignin content, respectively. Reduced levels of mineral N were associated with higher levels of biomass-N. The levels of N₂O-N lost from sugar beet residues on day 14 were significantly reduced from 66 to 5 g ha⁻¹ where compactor (cardboard) waste had been mixed into sandy loam, but this effect was not observed in the silt loam. These techniques could lead to greater efficiency of N use in rotations through reduction in N losses, and provide alternative routes for disposal of wastes when the EC Landfill Directive is implemented.