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A new diterpene dimer from the bark ofChamaecyparis obtusa
Authors:Nobuyasu Hanari  Hiroshi Yamamoto  Takashi Ooi  Takenori Kusumi  Ken -ichi Kuroda
Institution:(1) Institute of Agricultural and Forest Engineering, University of Tsukuba, 305-8572 Tsukuba, Japan;(2) Faculty of Education, Ibaraki University, 310-8512 Ibaraki, Japan;(3) Faculty of Pharmaceutical Sciences, Tokushima University, 770-8505 Tokushima, Japan
Abstract:This paper describes characterization of diterpenes of the bark of Japanese cypress,Chamaecyparis obtusa (S. and Z.) Endl, without the resinous stem canker to learn the difference between the cypress bark affected with the canker. A diterpene dimer and two diterpenes, 6agr,12-dihydroxyabieta-8,11,13-trien-7-one and 6,12-dihydroxyabieta-5,8,11, 13-tetraen-7-one, were firstly isolated from Japanese cypress. The dimer, 6-(abieta-6prime,8prime,11prime, 13prime-tetraenyl-12prime-oxy)-7-methoxyabieta-8,11,13-trien-12-ol, was a new compound. It is a terpene indicative ofC. obtusa not infected with the resinous stem canker. Five known diterpenes were also isolated.
Keywords:Diterpene dimer  Diterpene  Chamaecyparis obtusa  Resinous stem canker
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