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新型氯虫苯甲酰胺衍生物的合成及其杀虫活性
引用本文:李维洋,陈蔚燕,耿丙新,许良忠.新型氯虫苯甲酰胺衍生物的合成及其杀虫活性[J].农药学学报,2014,16(2):220-224.
作者姓名:李维洋  陈蔚燕  耿丙新  许良忠
作者单位:1.青岛科技大学 化学与分子工程学院 农用化学品研究所, 山东 青岛 266042
摘    要:以氯虫苯甲酰胺为先导,设计并合成了一系列结构新颖的邻氨基苯甲酰胺类衍生物,其结构均经核磁共振氢谱和质谱确证。初步杀虫活性测试结果表明,在质量浓度为1μg/mL时,部分化合物对小菜蛾Plutella xylostella的致死率均超过90%,高于先导化合物氯虫苯甲酰胺。

关 键 词:氯虫苯甲酰胺    异丙醇胺    甲基肼    杀虫活性
收稿时间:2013/11/10 0:00:00
修稿时间:2014/1/17 0:00:00

Synthesis and insecticidal activity of novel chlorantraniliprole derivatives
LI Weiyang,CHEN Weiyan,GENG Bingxin and XU Liangzhong.Synthesis and insecticidal activity of novel chlorantraniliprole derivatives[J].Chinese Journal of Pesticide Science,2014,16(2):220-224.
Authors:LI Weiyang  CHEN Weiyan  GENG Bingxin and XU Liangzhong
Institution:1.Institute of Agrochemicals, College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, Qingdao 266042, Shandong Province, China2.College of Chemistry and Pharmacy, Qingdao Agricultural University, Qingdao 266109, Shandong Province, China
Abstract:A series of novel chlorantraniliprole derivatives were designed and synthesized based on the structure of chlorantraniliprole. All the compounds were confirmed by 1H NMR and MS. The preliminary results of insecticidal activities indicate that some of the compounds display certain insecticide activities against Plutella xylostella under 1 μg/mL. Compounds 5a, 5'a, 4'a and 4'd showed comparatively higher activity than chlorantraniliprole.
Keywords:chlorantraniliprole  isopropanol  methyl hydrazine  insecticidal activity
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