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大气颗粒物中有机污染物及自由基的检测
引用本文:刘文霞 肖天存. 大气颗粒物中有机污染物及自由基的检测[J]. 河南农业大学学报, 1998, 32(4): 320-324,334
作者姓名:刘文霞 肖天存
作者单位:[1]河南农业大学林学园艺学院 [2]山东大学环境工程系
摘    要:采用毛细管气相色谱-色质联手技术,分析了济南地区大气瓢尘及降尘中有机污染物的化学组成,共检测出170多种有机污染物,包括烃,酸,酞酸酯,醇,醛,酮,酚,酰胺,苯,萘及其衍生物,硝基化合物,联苯及其衍生物,三苯,茚,芘,芴菲,蒽以及苯并芘等多环芳烃化合物。

关 键 词:大气颗粒物 有机污染物 自由基 检测

Determination of Organic Pollutants and Free Radical in Atmospheric Particulates
Liu Wenxia Xiao Tiancun Wang Xiuhong Wang Shuren. Determination of Organic Pollutants and Free Radical in Atmospheric Particulates[J]. Journal of Henan Agricultural University, 1998, 32(4): 320-324,334
Authors:Liu Wenxia Xiao Tiancun Wang Xiuhong Wang Shuren
Affiliation:Liu Wenxia 1 Xiao Tiancun 2 Wang Xiuhong 2 Wang Shuren 2
Abstract:The chemical composition of particulates and organic pollutants in TSP,precipatation matter of Jinan Area were studied with GC/MS.It's found there are more than 170 organic pollutants in the aerosol:hydrocarbons,acids,phthalates ,alchohols,aldehydes,ketones,phenol,amide,benzene,naphthalene and its derivative,nitro chemical compounds,biphenyl and its derivative,triphenyl,indene,pyrene,flaorene,anthracene,benzo and polycyclic aromatic hydrocarbon(PAH)compounds like pyrene.Free radical of various atmospheric aerosols was detected with Electron Spin Resonance(ESR).It's observed that humic acid free radical exists in TSP over the Refinery Plant,Power plant and Shandong University in Jinan,and that the free radical can exchange with water,dissolve partly in water and form a new free radical.
Keywords:atmospheric particulates  organic pollutants  free radical  GC/MS  ESR  
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