IRON AND ALUMINIUM AS CEMENTING SUBSTANCES OF SOIL AGGREGATES

A method is described for extracting fractions of soil iron and aluminium without removing organic matter. The extraction is by acetylacetone in a non–polar solvent and is virtually complete in zoo h. Similar amounts of iron and aluminium are extracted by acetylacetone in either benzene or water, but organic matter is extracted in detectable amounts only by acetylacetone in water. Extraction in aqueous solution after acetylacetone in benzene removes only organic matter, with no appreciable release of iron and aluminium. Metals extracted by acetylacetone in benzene are therefore considered to be bonded to that part of the organic matter which is extracted by acetylacetone. Water alone does not extract significant amounts of organic matter after removal of iron and aluminium by acetylacetone in benzene. The refolding of the hydrophilic surface units of the organic matter, caused by non–polar solvents, may hinder the extraction by water.