| 3-(2-丙烯基)苯甲基氯的合成 |
| |
| 引用本文： | 王亚飞,张成路,包丽影.3-(2-丙烯基)苯甲基氯的合成[J].黑龙江八一农垦大学学报,2002,14(4):90-93. |
| |
| 作者姓名： | 王亚飞 张成路 包丽影 |
| |
| 作者单位： | 黑龙江八一农垦大学基础部,密山,158308 |
| |
| 摘 要： | 本研究以间溴苯甲醛为原料,先用氢化铝锂还原得3-溴苯甲醇,然后保护羟基得甲氧基甲基(3-溴苄基)醚。将其先进行格氏化,再与丙酮反应得3-(2-羟基异丙基)甲氧基甲基醚,然后脱水得3-(2-丙烯基)苯甲醇.将其与氯化亚砜反应得目标产物3-(2-丙烯基)苯甲基氯。
|
| 关 键 词： | 三环二萜 合成 3-(2-丙烯基)苯甲基氯 |
| 文章编号： | 1002-2090(2002)04-0090-04 |
| 修稿时间： | 2002年9月12日 |
Synthesis of 3-(2-Propylen)benzyl chloride |
| |
| WANG Ya-fei,ZHANG Cheng-lu,BAO Li-ying.Synthesis of 3-(2-Propylen)benzyl chloride[J].Journal of Heilongjiang August First Land Reclamation University,2002,14(4):90-93. |
| |
| Authors: | WANG Ya-fei ZHANG Cheng-lu BAO Li-ying |
| |
| Abstract: | In this paper, 3-Bromobenaldehyde was used as the starting material which was reduced with LiAlH4 to get3-Bromobenzyl carbinol. The hydroxy of the compound 3-bromobenzyl carbinol was protected to attain compound methoxy-methy(3-bromobenzyl) ether. Compound was converted to Grignerd regeant and then reacted with Ketone to yield compound 3-(2-hydroxyiso propyl) methoxy-methy-ether. After dehydrotated and deprotected, we can get compound 3-(2-propylen) benzyl carbinol. The compound reacted with SOCl2 to give the title compound 3-(2-propylen) benzyl chloride. |
| |
| Keywords: | Tricyclic diterpene synthesis 3-(2-Propylen)benzyl chloride |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
