| 微波辐射下由酰氯合成酸酐 |
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| 引用本文： | 黄丹凤,施小宁,赵连彪,王进贤.微波辐射下由酰氯合成酸酐[J].甘肃农业大学学报,2003,38(3):311-314. |
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| 作者姓名： | 黄丹凤 施小宁 赵连彪 王进贤 |
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| 作者单位： | 1. 西北师范大学化学化工学院,兰州,730070
2. 西北师范大学化学化工学院,兰州,730070;甘肃农业大学基础科学系,兰州,730070 |
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| 基金项目： | 国家自然科学基金(20272049) |
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| 摘 要： | 试验探索了在微波辐射条件下,由酰氯和碳酸氢钠合成酸酐的最佳反应条件,结果表明以乙腈为溶剂,辐射功率P=525 W,辐射时间T=1 min时,即可生成高产率的酸酐,并在此条件下,合成了10种酸酐。
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| 关 键 词： | 酸酐 酰氯 微波辐射 合成 |
| 文章编号： | 1003-4315(2003)03-0311-04 |
Synthesis of anhydrides from acylchlorides under microwave irradiation |
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| HUANG Dan-feng,SHI Xiao-ning,ZHAO Lian-biao,WANG Jin-xian.Synthesis of anhydrides from acylchlorides under microwave irradiation[J].Journal of Gansu Agricultural University,2003,38(3):311-314. |
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| Authors: | HUANG Dan-feng SHI Xiao-ning ZHAO Lian-biao WANG Jin-xian |
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| Institution: | HUANG Dan-feng1,SHI Xiao-ning1,ZHAO Lian-biao1,2,WANG Jin-xian1 |
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| Abstract: | The experiment was carried out for investigating The reaction of acyl chlorides with NaHCO3 to preparing symmetrical anhydrides under microwave irradiation. The results indicated that CH3CN as solvent, microwave irradiation power P = 525 W, microwave irradiation time T=1 min, the yields of symmetrical anhydrides is highest. Under these conditions, ten symmetrical anhydrides were synthesized. |
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| Keywords: | anhydride acyl chloride microwave irradiation synthesis |
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