The Influences of Storage and Further Purification on Residual Concentrations of Pharmaceuticals and Phthalate Esters in Drinking Water

This paper reports about the modification of sand and fumed silica with titania in order to obtain a photocatalytic active material for the degradation of pollutants. The coating process was performed based on the sol–gel method. Tetrapropylorthotitanate was used as the titania precursor to apply a nanoscaled layer on sand grains. For silica fume, the coating process was varied. Various amounts of tetrapropylorthotitanate were used to obtain different coating thicknesses and to identify the maximum amount of titania that could be loaded on the material. All samples showed high photonic efficiencies in the degradation of nitrogen monoxide despite their low titania quantities, which were identified via x-ray fluorescence analysis. Some samples showed higher photonic efficiencies than commercial Degussa P25. Due to the preparation method, calcination of the sand composites was not necessary to yield a crystalline coating which was responsible for the high photocatalytic activity. However, silica fume composites had to be calcined possibly due to variation in the preparation method. Scanning electron micrographs revealed the structured morphology of all specimens. Energy dispersive x-ray analysis identified nanoscaled titania particles on the sand surface that could not be observed only via SEM. The results of this research are especially interesting for large scale applications of photocatalysts. As industrial sand and silica fume used are low cost materials, this new kind of photocatalyst can be applied in higher quantities and distributed onto larger areas, while saving costs at the same time.