Seasonal variations in nitrate leaching in structured clay soils under mixed land use

Nitrate leaching was studied for 2 years in a structured clay soil (Evesham series) under grass, winter wheat and spring barley at N fertilizer inputs of 135–144 kg ha^?1 year^?1. Measurements of soil water to 2 m depth by neutron probe showed that the year could be divided into well defined periods of deficit, separated by a period when the soil was at its winter mean water content. Soil water potentials showed very little gradient for water flow below 1 m, and a persistent convergent zero flux plane at 40–60 cm depth during the autumn wetting-up period (September—November).Nitrate concentration in the drainage increased with discharge rates up to 3–6 mm day^?1. Mean nitrate concentrations were generally highest during intermittent drain-flow in the autumn. Of the total N leached over the 2 years, 23 to 28% (5–7 kg N ha^?1) was lost during this period. The remainder (13–25 kg N ha^?1) was leached during winter and virtually no N was lost in the following spring-early summer. This seasonal pattern of N leaching was interpreted in terms of intermittent flow during rainfall of nitrate-rich water from surface layers, which bypassed the relatively dry soil matrix at 40–60 cm, but was intercepted by natural and artificial drainage channels. Implications for the prediction of N leaching loss based on the concept of excess winter rainfall are discussed. When predicting the start of N leaching in structured clay soils, the soil water status should be assessed from measurements of water potential rather than water content.