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Dimensional stability of wood acetylated with acetic anhydride solution of glucose pentaacetate
Authors:Eiichi Obataya   Masaki Sugiyama  Bunichiro Tomita
Affiliation:(1) Institute of Agricultural and Forest Engineering, University of Tsukuba, Tsukuba, 305-7235 Ibaraki, Japan;(2) Forestry and Forest Products Research Institute, 305-8687 Ibaraki, Japan;(3) Present address: UM2-LMGC-Bois, CC81 Pl. E. Bataillon, 34095 Montpellier, cdx 5, France
Abstract:Five wood species were acetylated with acetic anhydride (AA) solution of glucose pentaacetate (GPA) at 120°C for 8h, and the effect of GPA on the dimensional stability of the acetylated wood was investigated. Some GPA was introduced into the wood cell wall during acetylation. The GPA remaining in the cell lumen penetrated the cell wall effectively after heating to more than 140°C for 10min. The bulking effects of GPA resulted in a 10%–30% increase in the anti-swelling efficiency of the acetylated wood with 20% GPA/AA solution in place of AA. Hydrophobic GPA did not deliquesce under highly humid conditions and it remained in the cell wall after boiling in water.Part of this paper was presented at the 51st Annual Meeting of the Japan Wood Research Society, Tokyo, April 1988
Keywords:Acetylation  Glucose pentaacetate  Bulkingeffect  Dimensional stability
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