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| 甲羧除草醚的合成 | |
| 引用本文： | 薛超,宁斌科,刘军,雷昭.甲羧除草醚的合成[J].农药科学与管理,2011,32(3):20-22. |
| 作者姓名： | 薛超 宁斌科 刘军 雷昭 |
| 作者单位： | 1. 西安近代化学研究所农药事业部,陕西,西安,710065;西安交通大学化工学院,陕西,西安,710000 2. 西安近代化学研究所农药事业部,陕西,西安,710065 3. 西安交通大学化工学院,陕西,西安,710000 |
| 摘 要： | 介绍了甲羧除草醚的合成方法。以间氯苯甲酰氯、异丙醇酯化生成氯苯甲酰异丙酯,然后经硝化、缩合醚化,酯交换共4步反应得到了2,4-二氯苯基-3’-甲氧基甲酰基-4’-硝基苯基醚。该方法避免了其它路线的种种缺点,具有收率高、产品纯度高和成本低等优点,合成总收率为(以间氯苯甲酰氯计)72.4%,产品纯度达到97.6%。最终目标产物结构通过红外IR、核磁共振H’NMR进行了表征。 |
| 关 键 词： | 除草剂 甲羧除草醚 合成路线 酯交换 |
Synthesis of Bifenox |
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| Xue Chao,Ning Binke,Liu Jun,Lei Zhao.Synthesis of Bifenox[J].Pesticide Science and Administration,2011,32(3):20-22. | |
| Authors: | Xue Chao Ning Binke Liu Jun Lei Zhao |
| Institution: | Xue Chao,Ning Binke,Liu Jun(Department of Pesticide,Xi'an Modern Chemistry Research Institute,Xi'an 710065,China) Lei Zhao(School of Chemical Engineering,Xi'an Jiaotong University,Xi'an 710000,China) |
| Abstract: | This paper introduced three synthesis routes of bifenox.The m-chloro isopropyl benzoate was synthesized from 3-Chlorobenzoyl chloride and isopropanol;after nitrification,etherification,transesterification,the methyl 5-(2,4-dichlorophenoxyl)-2-nitrobenzoate was prepared.The total yield rate of product using this synthesis route was 72.4%,the purity of the final product was 97.6%.The structure of objective product was characterized by H'NMR and FTIR. |
| Keywords: | bifenox synthesis transesterification |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |