Capacitive behaviors and monomer concentration effects of poly(9-benzyl-9<Emphasis Type="Italic">H</Emphasis>-carbazole) on carbon fiber microelectrode |
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Authors: | Murat Ates Nesimi Uludag |
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Institution: | (1) Present address: Department of Chemistry, Faculty of Arts and Sciences, Namik Kemal University, Namik Kemal Street, Number:14, 59100 Tekirdag, Turkey;(2) Department of Chemistry, Polymer Science and Technology, Istanbul Technical University, Maslak, 34469 Istanbul, Turkey |
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Abstract: | In this work, 9-benzyl-9H-carbazole (BzCz) monomer was chemically synthesized by a new process. It was electrocoated on carbon fiber microelectrode
(CFME) as an active electrode material in 0.1 M sodium perchlorate (NaClO4)/acetonitrile (ACN) solution. The electropolymerization process was successfully performed less amount of 3 mM. The characterization
of Poly(BzCz)/CFME thin films was performed by Fourier transform infrared reflectance-attenuated total reflection spectroscopy
(FTIR-ATR) and Electrochemical impedance spectroscopy (EIS). The effects of monomer concentrations (1, 2, and 3 mM) during
the preparation of modified electrodes were examined by EIS. Capacitive behaviors of modified CFMEs were defined via Nyquist,
Bode-magnitude and Bode-phase plots. Variation of capacitance values by initial monomer concentration and specific capacitance
values are presented. The highest specific capacitance value for a potensiodynamically prepared polymer thin film in the initial
monomer concentration of 1 mM with a charge of 4.54 mC cm−2 was obtained about 221.4 μF cm−2. An equivalent circuit model, R(C(R(QR)))(CR), for different concentrations of Poly(BzCz). CFME was proposed and experimental
data were simulated to obtain the numerical values of circuit components. |
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