Spatial variability of solutes in a pecan orchard surface-irrigated with untreated effluents in the upper Rio Grande River basin

Untreated effluents are blended with water from the Rio Grande River and used for irrigation in the Juarez Valley of northern Mexico. Effluents are a source of nutrients, but may also be a source of heavy metal contamination. This study was conducted to characterize deposition patterns of selected metals, salts, and total nitrogen in a 6 ha pecan (Carya illinoenisis K.) orchard which had healthy-to-stunted trees with dieback. Orchard soil was collected along multiple transects to depths of 1.2 m, with spacing every 20 m. All solutes showed a magnitude variability in particular ions. Chromium, Ni, Pb, and Cd concentrations averaged <14 mg kg^?1. Soil Na, Ca, K, Mg, SO₄, Cl and NO₃–N averaged <100 mg kg^?1. Total N was <0.21%. Most solutes accumulated at the soil surface with the exception of Na and SO₄. Linear semi-variograms best described spatial metal deposition and surface clay content with a range of influence >189 m. Spherical semi-variograms best described spatial distribution of salts and total N, but accounted <50% of the variability. The solubility of solutes in moderately alkaline irrigation water and their specific behavior in calcareous soils likely affected deposition patterns. Estimated metal loads from irrigation over a 15-year period were <3 kg ha^?1, but about 187 Mg ha^?1 for total dissolved solids (salts). Pecan leaf tissue showed no signs of heavy metal accumulation. Suboptimum pecan growth was associated with salt accumulation in a clayey area with low permeability. Salts, in particular Na, rather than metals may be the most important inorganic contaminants for irrigated agriculture in this region. Salt loads in irrigation waters are expected to increase as agriculture increasingly relies on urban effluents too expensive to convert to potable water.