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乌桕梓油酸碱催化法制备生物柴油的研究
引用本文:吴开金,黄勇,肖祥希,何文广,张彪. 乌桕梓油酸碱催化法制备生物柴油的研究[J]. 福建林业科技, 2011, 38(3). DOI: 10.3969/j.issn.1002-7351.2011.03.13
作者姓名:吴开金  黄勇  肖祥希  何文广  张彪
作者单位:1. 福建省林业科学研究院,福建福州,350012
2. 福建师范大学生命科学学院,福建福州,350108
基金项目:福建科技重大专项,1,福建省森林培育和林产品加工利用重点实验室共同资助项目
摘    要:以乌桕梓油为原料,采用酸碱催化法制备生物柴油,探讨温度、醇油比、催化剂含量等因素,在碱催化酯交换反应过程中对生物柴油转化率的影响。结果表明,随着温度、醇油比、催化剂含量的升高,乌桕梓油的转化率呈上升的趋势;在温度60℃,醇油比6∶1,KOH 1%的条件下,生物柴油的转化率可达98.84%,基本性质符合生物柴油的国家标准和0#柴油的国家标准。表明,乌桕籽可以作为制备生物柴油的一种良好原料。

关 键 词:乌桕梓油  酯化  酯交换  生物柴油

Research on Biodiesel Production from Tallow Kernel Oil by Acid-Alkali Catalysis Process
WU Kai-jin,HUANG Yong,XIAO Xiang-xi,HE Wen-guang,ZHANG Biao. Research on Biodiesel Production from Tallow Kernel Oil by Acid-Alkali Catalysis Process[J]. Journal of Fujian Forestry Science and Technology, 2011, 38(3). DOI: 10.3969/j.issn.1002-7351.2011.03.13
Authors:WU Kai-jin  HUANG Yong  XIAO Xiang-xi  HE Wen-guang  ZHANG Biao
Abstract:Tallow kernel oil was used to prepare biodiesel by acid-alkali catalysis process.The effects of temperature,ratio of methanol to oil,concentration of catalyst on biodiesel transform rate were discussed during alkali catalysis and transesterification.The results showed that as the increase of temperature,ratio of methanol to oil,concentration of catalyst,the yield of transform rate increased.Under the optimum condition:temperature 60 ℃,ratio(6∶ 1)of methanol to oil,concentration(1%)of KOH,the yield of transform of biodiesel reached to 98.84%,which accorded with the standard of biodiesel and 0# diesel oil national standards.Therefore,the seed of kernel was excellent material for preparing biodiesel.
Keywords:tallow kernel oil  esterify  transesterification  biodisel
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