中国某些土壤中的水溶性稀土元素

Water-soluble rare earth elements (WSREEs) of four typical soil profiles in China were determined by using a high-resolution inductively coupled plasma mass spectrometer. Results showed that the contents of WSREEs decreased from upper layer to lower layer of soils in the southern part of China with a high rainfall and low pH but increased for soils in the northern part of China with a low rainfall and relatively higher pH. Contents of WSREEs in soils were lower than 100 μg kg^-1 in most cases, and varied greatly with both different soils and different layers of the same profile. The highest content was 2816.3 μg kg^-1 but the lowest was 17.6 μg kg^-1 only. The content of individual rare earth lement (REE) in the soil solution also varied greatly with the highest one ranging from 8.4 to 1373 μg kg^-1 for Ce and the lowest one from 0.05 to 4.48 μg kg^-1 for Lu. The sum of WSREEs in the first soil layers ranged from 121.5 to 345.6 μg kg^-1. Great variations existed among ratios of REEs extracted with water to the total REEs of soils, ranging from 0.02×10^-3 to 13.2×10^-3. But as the upper layer was considered, the ratio showed only a small difference, ranging from 0.79×10^-3 to 1.69×10^-3.

Water-soluble rare earth elements in some soils of China