Synthesis and electropolymerization of 9-(4-vinylbenzyl)-9H-carbazole on carbon fiber microelectrode: Capacitive behavior of poly(9-(4-vinylbenzyl)-9H-carbazole) |
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Authors: | Murat Ates Nesimi Uludag |
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Institution: | (1) Present address: Department of Chemistry, Faculty of Arts and Sciences, Namik Kemal University, Namik Kemal Street, Number:14, 59100 Tekirdag, Turkey;(2) Department of Chemistry, Polymer Science and Technology, Istanbul Technical University, Maslak, 34469 Istanbul, Turkey |
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Abstract: | The synthesis of 9-(4-vinylbenzyl)-9H-carbazole (VBCz) monomer and surface characterizations of thin film coating of poly(9-(4-vinylbenzyl)-9H-carbazole), P(VBCz) homopolymer on carbon fiber microelectrode (CFME) was performed. Coatings of polymer thin films obtained,
with different initial monomer concentrations, were characterized by cyclic voltammetry, scanning electron microscopy and
Fourier transform infrared reflectance-attenuated total reflection spectroscopy. Different initial monomer concentrations
(1, 3, 5, and 10 mM) were electrodeposited in 0.1 M lithium perchlorate/acetonitrile solution. The characterization of the
thin polymer films was performed on the surface of carbon fiber, and composition of polymeric structure was proposed. Capacitor
behavior of modified CFME was studied by electrochemical impedance spectroscopy. The deposition charge of polymer growth affected
the redox parameters of resulting coated CFME. |
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Keywords: | |
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