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Enhanced thermal transport performance for poly(vinylidene fluoride) composites with superfullerene
Authors:Yuming Wu  Yong Cao  Xueshan Xiao  Zhiduo Liu  Mengjie Wang  Nan Jiang  Xinfeng Wu  Cheng-Te Lin  Jinhong Yu
Affiliation:1.Laboratory for Microstructures, Institute of Materials,Shanghai University,Shanghai,China;2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering,Chinese Academy of Sciences,Ningbo,China;3.College of Ocean Science and Engineering,Shanghai Maritime University,Shanghai,China
Abstract:High thermal conductive polymer composites have recently attracted much attention, along with the quick development to the electronic devices toward higher speed. The addition of high thermal conductive fillers is an efficient method to solve this problem. Here, we introduced superfullerene (SF), a novel zero-dimensional carbon-based filler, and incorporated into PVDF by a solution method. The effects of SF filler on the thermal conductivity of PVDF composites were systematically investigated. It was found that PVDF composites exhibited an improvement in thermal conductivity at a low SF loading. PVDF composites with only 5 wt% SF filler present the thermal conductivity value of 0.365 Wm-1K-1, which is as much as 121 % enhancement in comparison with that of neat PVDF. In view of the excellent thermal transport performance, the composites may enable some applications in thermal management in the future.
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