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Antibacterial,UV protective and ammonia sensing functionalized polyester fabric through in situ synthesis of cuprous oxide nanoparticles
Authors:Ali Bashiri Rezaie  Majid Montazer  Mahnaz Mahmoudi Rad
Affiliation:1.Department of Textile Engineering,Amirkabir University of Technology,Tehran,Iran;2.Department of Textile Engineering, Functional Fibrous Structures & Environmental Enhancement (FFSEE), Amirkabir Nanotechnology Research Institute (ANTRI),Amirkabir University of Technology,Tehran,Iran;3.Skin Research Centre,Shahid Beheshti University of Medical Sciences,Tehran,Iran
Abstract:In this research, a facile and cost effective method is presented for in-situ synthesis of cuprous oxide nanoparticles on polyester fabric along with surface modification by using one pot wet chemical method at boil. Copper sulfate (CuSO4), sodium hypophosphite (SHP) and polyvinylpyrrolidone (PVP) were used as precursor, reducing agent and stabilizer, respectively. Further, monoethanolamine (MEA) was used as pH adjustment and also modifier of polyester surface introduced amide and hydroxyl functional groups on the fabric. The images of FESEM, mapping, patterns of EDX, UV-visible absorbance spectrum, FTIR analysis and X-ray diffraction pattern confirmed the successful processing. The treated samples showed excellent antibacterial properties (100 %) toward both Staphylococcus aureus and Escherichia coli pathogen bacteria. Also, the results of cytotoxicity test proved no harmful effects on the human dermal fibroblasts for the treated sample with the lower concentration of the materials having white color with good antibacterial activities. The treated samples also indicated very good UV protection properties as well as improved wettability and mechanical properties. They are also sensitive to ammonia through immediate color change when contacted with ammonia solution. The above mentioned processing method can be used for production of polyester fabric with multifunctional properties for using in the various textile industries.
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