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活性炭催化臭氧化降解亚甲基蓝实验
引用本文:刘占孟,唐朝春,李静,鲍东杰.活性炭催化臭氧化降解亚甲基蓝实验[J].浙江林学院学报,2009,26(3):406-410.
作者姓名:刘占孟  唐朝春  李静  鲍东杰
作者单位:1. 华东交通大学,土木建筑学院,江西,南昌,330013
2. 邢台职业技术学院建,建工系,河北,邢台,054035
基金项目:江西省教育厅资助项目 
摘    要:研究了活性炭催化臭氧化降解模拟染料废水亚甲基蓝溶液,考察了臭氧化空气流量、pH值、废水初始质量浓度和活性炭用量等因素对处理效果的影响。结果表明:该法可有效去除有机物,废水在低质量浓度、碱性条件下对反应有利;在亚甲基蓝初始质量浓度100mg·L^-1,pH9.5,活性炭9g·L^-1,反应90min条件下,色度去除率达到了95.6%,化学需氧量(COD)去除率达到了64.8%;活性炭催化臭氧化废水以间接氧化为主,活性炭可促进臭氧化过程产生·OH自由基并提高其利用率,相对于单独臭氧化过程,废水COD去除率可显著提高。

关 键 词:环境保护学  催化臭氧化  活性炭  亚甲基蓝  有机废水

Catalytic ozonation with activated carbon for degradation of methylene blue in wastewater
LIU Zhan-meng,TANG Chao-chun,LI Jing,BAO Dong-jie.Catalytic ozonation with activated carbon for degradation of methylene blue in wastewater[J].Journal of Zhejiang Forestry College,2009,26(3):406-410.
Authors:LIU Zhan-meng  TANG Chao-chun  LI Jing  BAO Dong-jie
Institution:LIU Zhan-meng, TANG Chao-chun, LI Jing, BAO Dong-jie(1. School of Civil Engineering and Architecture, East China Jiaotong University, Nanchang 330013, Jiangxi, China; 2. Department of Building Engineering, Xingtai Vocational and Technical College, Xingtai 054035, Hebei, China)
Abstract:The effect of ozoniferous air flux, pH, as well as initial concentration and quantity of activated carbon for degradation of a simulated dye wastewater of methylene blue was studied. Experimental results indicated that methylene blue wastewater was effectively decomposed using a low initial concentration of methylene blue and a high pH. For 90 min at an initial concentration of 100 mg·L^-1 of methylene and pH of 9.5 with 9 g·L^-1 of activated carbon, the removal rate for color was 95.6% and for the chemical oxygen demand (COD) was 64.8%. Activated carbon not only accelerated the generation of "OH radicals, but also enhanced their reaction with methylene blue so that in the process of catalytic ozonation with activated carbon, indirect oxidation dominated. Compared with a single ozonation, the removal rate of COD was heightened.
Keywords:environmental protection  catalytic ozonation  activated carbon  methylene blue  organicwastewater
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