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Synthesis and application of alkyl-substituted high chroma yellow dyes for unmodified polypropylene fiber
Authors:Taekyeong Kim  Jongsuc Jung  Kyungjin Jang  Seokhan Yoon  Mikyung Kim
Affiliation:(1) Department of Textile System Engineering, College of Engineering, Kyungpook National University, Daegu, 702-701, Korea;(2) Department of Advanced Organic Materials Science and Engineering, Kyungpook National University, Daegu, 702-701, Korea;(3) Korea Dyeing Technology Center, Daegu, 703-834, Korea
Abstract:A series of new monoazo yellow dyes having different alkyl substituents was synthesized to dye unmodified polypropylene fiber. Color hue of the dyes exhibited light yellow with very high chroma enough to use as yellow primary color dyes. The affinity of the dyes onto unmodified polypropylene was increased with the increase of the length of alkyl substituents. Therefore, the hexyl-substituted dye having the longest alkyl group in this experiment showed very high color strength of dyeings with K/S value of over 26 at maximum absorption wavelength. The color fastnesses to washing, rubbing and light were also improved significantly for the longer alkyl substituted dyes, so that the hexyl-substituted dye exhibited a rating higher than 4∼5 for all kinds of fastnesses.
Keywords:Polypropylene  Disperse dye  Hydrophobicity  Alkyl substitution  Dyeing
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