A simple process-based model for estimating ammonia emissions from agricultural land after fertilizer applications

Abstract. Fertilizer applications to agricultural land are a significant source of ammonia (NH₃) emission to the atmosphere, accounting for approximately 10% of the total emissions from agriculture. Current estimates of emissions from fertilizer applications use 'fixed' emission factors. This paper describes a model in which the emission factors are expressed as a function of the important influencing variables: fertilizer type, soil pH, land use, application rate, rainfall and temperature. Total emission in 2002 for the UK were estimated by running the model for a 'standard UK' scenario, viz. 28.7 kt NH₃-N, which compares well with the UK inventory estimate of 30.4 kt NH₃-N. Differences exist in the estimates for specific fertilizer types, with the mean emission factor for urea applications to grassland, in particular, being lower by use of this model (13% compared with 23% of applied N for the UK inventory). Emission estimates were most sensitive to temperature and fertilizer type. Scenario testing showed that significant reductions in emission could be achieved by replacing urea with other forms of N fertilizer, by combining urea use with a urease inhibitor, or by modifying some management practices.