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Characteristics and Performance Of Novel Water-Absorbent Slow Release Nitrogen Fertilizers
作者姓名:HE  Xu-sheng  LIAO  Zong-wen  HUANG  Pei-zhao  DUAN  Ji-xian  GE  Ren-shan  LI  Hong-bo  GENG  Zeng-chao
作者单位:[1]Postdoctorate Exchange Centre for Plant Protection, South China Agricultural University, Guangzhou 510642, P.R.China [2]Enterprise Postdoctorate Centre for Batian Eco-Engineering Co., Shenzhen 518105, P.R.China [3]College of Resources and Environment Science, Northwest A&F University, Yangling 712100, P.R.China
摘    要:In this article, a research on the characteristics and performance of water-absorbent slow release nitrogen fertilizer (WASRNF) using infrared spectroscopy (IR), scanning electronic microscopy (SEM), differential scanning calorimetry (DSC), and thermogravimetry analysis (TGA), was present. The results indicate that the water absorbency and nitrogen analysis of WASRNF is 103 g g^-1 and 30%, respectively, and WASRNF exhibits approximately neutral pH and very low salt index. WASRNF is a copolymer of nitrogen fertilizer and super absorbent polymer (SAP) monomers which is formed through hydrogen bond interaction, and the molecule contains hydrophilic groups, which is responsible for the absorption and water retention capacity of the molecule. WASRNF is a gel that exhibits the ability to swell, but does not dissolve in water. WASRNF shows non-homogenous nature as a whole, but in local zone it is homogenous, the copolymer molecule shows chain network that is the physical structure responsible for absorption and retention of water in WASRNF. The water retained in WASRNF exists as free and nonfreezing bound and freezing bound water states, with the free and the nonfreezing water accounting for more than 95% of water retained in WASRNF, and the nonfreezing bound water for less than 5%. WASRNF functions in delaying the release of nitrogen from it, thereby serving a novel slow release nitrogenous fertilizer.

关 键 词:氮肥  缓慢释放  吸水剂  释放性能

Characteristics and Performance of Novel Water-Absorbent Slow Release Nitrogen Fertilizers
HE Xu-sheng LIAO Zong-wen HUANG Pei-zhao DUAN Ji-xian GE Ren-shan LI Hong-bo GENG Zeng-chao.Characteristics and Performance Of Novel Water-Absorbent Slow Release Nitrogen Fertilizers[J].Agricultural Sciences in China,2007,6(3):338-346.
Authors:HE Xu-sheng  LIAO Zong-wen  HUANG Pei-zhao  DUAN Ji-xian  GE Ren-shan  LI Hong-bo  GENG Zeng-chao
Institution:1. Postdoctorate Exchange Centre for Plant Protection, South China Agricultural University, Guangzhou 510642, P.R. China;Enterprise Postdoctorate Centre for Batian Eco-Engineering Co., Shenzhen 518105, P.R. China;College of Resources and Environment Science, Northwest A&F University, Yangling 712100, P.R. China
2. Postdoctorate Exchange Centre for Plant Protection, South China Agricultural University, Guangzhou 510642, P.R. China
3. Enterprise Postdoctorate Centre for Batian Eco-Engineering Co., Shenzhen 518105, P.R. China
4. College of Resources and Environment Science, Northwest A&F University, Yangling 712100, P.R. China
Abstract:In this article, a research on the characteristics and performance of water-absorbent slow release nitrogen fertilizer (WASRNF)using infrared spectroscopy (IR), scanning electronic microscopy (SEM), differential scanning calorimetry (DSC), and thermogravimetry analysis (TGA), was present. The results indicate that the water absorbency and nitrogen analysis of WASRNF is 103 g g-1 and 30%, respectively, and WASRNF exhibits approximately neutral pH and very low salt index.WASRNF is a copolymer of nitrogen fertilizer and super absorbent polymer (SAP) monomers which is formed through hydrogen bond interaction, and the molecule contains hydrophilic groups, which is responsible for the absorption and water retention capacity of the molecule. WASRNF is a gel that exhibits the ability to swell, but does not dissolve in water.WASRNF shows non-homogenous nature as a whole, but in local zone it is homogenous, the copolymer molecule shows chain network that is the physical structure responsible for absorption and retention of water in WASRNF. The water retained in WASRNF exists as free and nonfreezing bound and freezing bound water states, with the free and the nonfreezing water accounting for more than 95% of water retained in WASRNF, and the nonfreezing bound water for less than 5%. WASRNF functions in delaying the release of nitrogen from it, thereby serving a novel slow release nitrogenous fertilizer.
Keywords:water-absorbent slow release nitrogen fertilizer  characteristics  performance
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