Determination of silver in soils by atomic absorption spectrometry

A method for the determination of Ag in soils using atomic absorption spectrometry is described. The method involves the extraction of Ag from soil by boiling with 6 M HC1 followed by separation of the extracted Ag into methylisobutylketone (MIBK) using sodium N, N-diethyldithiocarbamate (DDTC) as a complexing agent. Silver is determined in the MIBK by direct aspiration into a flame atomic absorption spectrophotometer. The detection limit (S/N=2) for this method is 0.0001 mg L^?1 for aqueous solution and 0.002 mg kg^?1 for soil. The Ag content of even unpolluted soils can be determined by this method. The determination of Ag using this method was shown to be unaffected by the presence of various ions in the soil. The method was able to recover nearly 100% of Ag added to soil and approximately the same amounts of soil Ag were determined using this method as with HF-H₂SO₄ decomposition. For 3 reference soils of the Canadian Certified Reference Materials Project (CCRMP), the Ag values obtained by this method were the same as the values determined by Ebarvia et al. (1988). The amounts of Ag in the soils sampled in the Ichi River basin and the Ichi River sediments were determined using this method. This area has been polluted by Cd, Cu, Pb, and Zn discharged from the Ikuno Mine and Smelter. The Ag values ranged from 0.27 to 6.89 mg kg^?1 which were much higher than the values of the unpolluted soils.