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原位土壤溶液采样及可溶性有机碳(DOC)的紫外吸收光谱直接测定探讨
引用本文:罗小三,仓龙,郝秀珍,李连祯,周东美. 原位土壤溶液采样及可溶性有机碳(DOC)的紫外吸收光谱直接测定探讨[J]. 土壤, 2007, 39(6): 943-947
作者姓名:罗小三  仓龙  郝秀珍  李连祯  周东美
作者单位:1. 土壤与农业可持续发展国家重点实验室(中国科学院南京土壤研究所),南京,210008;中国科学院研究生院,北京,100049
2. 土壤与农业可持续发展国家重点实验室(中国科学院南京土壤研究所),南京,210008
基金项目:国家重点基础研究发展计划(973计划);中国科学院知识创新团队国际合作伙伴计划项目
摘    要:首次采用管壁过滤孔径为微米级(0.1~0.3μm)的水处理用多孔聚丙烯(腈)空心纤维细管,与注射器或真空管相连,自制成土壤溶液采样器,将空心纤维管埋置或插入土壤中抽取层面土壤溶液,所得溶液无须过滤即可进行各种理化分析和测定,且可连续采样,提出了一种价廉实用的原位土壤溶液取样方法。并根据可溶性有机碳(DOC)在紫外光区的吸收特征,将土壤溶液在254nm波长处的吸光度(UVA254)与DOC浓度(TOC仪法)进行比较,发现两者有较好的相关性(DOC=38.84×UVA254,n=37,R2=0.82),即直接测定土壤溶液的UVA254,再乘以系数38.84可以估算DOC浓度。与复杂的氧化-比色和昂贵的TOC仪测定法对比,UVA254能快速便捷地估计土壤溶液中DOC的浓度。UVA254也适用于水体DOC的估计。

关 键 词:原位土壤溶液采样器  可溶性有机碳(DOC)  紫外分光光度法

In-Situ Sampling of Soil Solution and Determination of Dissolved Organic Carbon (DOC) with UV Absorption Method (UVA254)
LUO Xiao-san,CANG Long,HAO Xiu-zhen,LI Lian-zhen and ZHOU Dong-mei. In-Situ Sampling of Soil Solution and Determination of Dissolved Organic Carbon (DOC) with UV Absorption Method (UVA254)[J]. Soils, 2007, 39(6): 943-947
Authors:LUO Xiao-san  CANG Long  HAO Xiu-zhen  LI Lian-zhen  ZHOU Dong-mei
Affiliation:State Key Laboratory of Soil and Sustainable Agriculture(Institute of Soil Science, Chinese Academy of Sciences), Nanjing 210008, China;Graduate School of the Chinese Academy of Sciences, Beijing 100049, China,State Key Laboratory of Soil and Sustainable Agriculture(Institute of Soil Science, Chinese Academy of Sciences), Nanjing 210008, China;Graduate School of the Chinese Academy of Sciences, Beijing 100049, China,State Key Laboratory of Soil and Sustainable Agriculture(Institute of Soil Science, Chinese Academy of Sciences), Nanjing 210008, China;Graduate School of the Chinese Academy of Sciences, Beijing 100049, China,State Key Laboratory of Soil and Sustainable Agriculture(Institute of Soil Science, Chinese Academy of Sciences), Nanjing 210008, China;Graduate School of the Chinese Academy of Sciences, Beijing 100049, China and State Key Laboratory of Soil and Sustainable Agriculture(Institute of Soil Science, Chinese Academy of Sciences), Nanjing 210008, China
Abstract:
Keywords:UVA254
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