| cis-丙环唑的制备及其晶体结构的研究 |
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| 引用本文： | 罗金香,杨春龙. cis-丙环唑的制备及其晶体结构的研究[J]. 农药学学报, 2006, 8(1): 20-24 |
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| 作者姓名： | 罗金香 杨春龙 |
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| 作者单位： | 1.南京农业大学 理学院, 江苏 南京 210095 |
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| 摘 要： | 采用丙环唑与硝酸成盐法和硅胶柱层析法制备了cis-丙环唑,并培养出单晶,用X射线单晶衍射法确定了其立体结构。晶体属单斜晶系,P21/c空间群,晶胞参数 a=1.065 3(3) nm,b=1.894 0(6) nm,c=0.810 4(3) nm, β=100.032(6)°,Z= 4,V= 1.610 0(9) nm3, Dc=1.412 g/cm3, F(000)=712,u=0.413 mm-1,R=0.066 2,wR=0.136 9。
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| 关 键 词： | cis-丙环唑 制备 晶体结构 |
| 文章编号： | 1008-7303(2006)01-0020-05 |
| 收稿时间： | 2005-08-01 |
| 修稿时间： | 2005-11-20 |
Study on Preparation and Crystal Structure of cis-Propiconazole |
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| LUO Jin-xiang and YANG Chun-long. Study on Preparation and Crystal Structure of cis-Propiconazole[J]. Chinese Journal of Pesticide Science, 2006, 8(1): 20-24 |
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| Authors: | LUO Jin-xiang and YANG Chun-long |
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| Affiliation: | 1.College of Science,Nanjing Agricultural University,Nanjing 210095,China |
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| Abstract: | cis-Propiconazole has been prepared by the methods of salt formation with nitric acid and silica gel column chromatography.Its structure was determined by X-ray diffraction analysis. The single crystal belongs to monoclinic system with space group P21/c,a =1.065 3(3) nm,b=1.894 0(6) nm, c=0.810 4(3) nm, β=100.032(6)°,Z = 4,V=1.610 0(9) nm3, Dc=1.412 g/cm3,F(000) = 712,u =0.413 mm-1,R=0.066 2, wR=0.136 9. |
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| Keywords: | cis-propiconazole preparation crystal structure |
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