Design, synthesis, and insecticidal activities of novel monohalovinylated pyrethroids |
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| Authors: | Zheng Zubiao Wang Jing Zhang Deyan Guan Xixia Gao Shuxu Chen Zizhan Zou Xinzhuo |
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| Institution: | Department of Chemistry, East China Normal University , Shanghai 200062, China. |
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| Abstract: | A series of novel monohalovinylated pyrethroids are designed and synthesized to replace one halo atom with a hydrogen atom on the double bond of dihalopyrethroids. Bioassays indicate that some of the synthesized compounds, such as 3j and 1j, exhibit high insecticidal activities against mosquitoes ( Culex pipiens pallens ), oriental armyworms ( Mythimna separata ), alfalfa aphids ( Aphis medicagini ), and carmine spider mites ( Tetranychus cinnabarinus ). Photolytic results of E-cis-1j suggest that monohalovinylated pyrethroids are photodegraded more easily than compound 12. |
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