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不同温·湿度下啶虫脒在褐土中降解研究
引用本文:张海松,李慧冬,陈子雷,丁瑞艳.不同温·湿度下啶虫脒在褐土中降解研究[J].安徽农业科学,2010,38(22):11984-11984,12262.
作者姓名:张海松  李慧冬  陈子雷  丁瑞艳
作者单位:山东省农业科学院中心实验室,山东省食品质量与安全检测技术重点实验室,农业部食品质量监督检验测试中心,山东济南,250100
基金项目:山东省农科院青年基金资助项目,山东省科技专项 
摘    要:目的]研究褐土中啶虫脒在不同温湿下的室内降解趋势,寻求最佳降解温度和湿度。方法]土壤中啶虫脒经乙腈高速匀浆提取后,减压浓缩,弗罗里硅土柱净化后GC-ECD进样。结果]在25℃20%、40%、60%含水量的情况下,啶虫脒的消解符合一级动力学方程,分别为C=3.1921e-0.145t,T1/2=4.8d;C=1.604e-0.231t,T1/2=3.0d;C=3.1329e-0.1564t,T1/2=4.4d。在含水量为40%的情况下,对其20、25、30℃的消解进行了测定,其消解也符合一级动力学方程,分别为C=2.3041e-0.1463t,T1/2=4.7d;C=1.604e-0.231t,T1/2=3.0d;C=0.7029e-0.2314t,T1/2=2.9d。结论]在30℃、含水量40%的情况下,降解最快。

关 键 词:啶虫脒  降解  褐土

Research on Acetamiprid Degradation in Brown Soil under Different Temperature and Humidity
Zhang Hai-song et al.Research on Acetamiprid Degradation in Brown Soil under Different Temperature and Humidity[J].Journal of Anhui Agricultural Sciences,2010,38(22):11984-11984,12262.
Authors:Zhang Hai-song
Institution:Zhang Hai-song et al (Central Laboratory Sh,ong Academy of Agricultural Sciences,Key Laboratory of Detection Technology Sh,ong Food Quality , Safety,Food Quality Supervision , Testing Center of Ministry of Agriculture,Jinan,Sh,ong 250100)
Abstract:Objective] The aim of the research was to seek a good temperature and humidity to study the degradation of acetamiprid in brown soil.Method] Acetamiprid were extracted by acetonitrile and homogenize,purified and concentrated by florisil,and then determined by GC with ECD-detector.Result]The results were C=3.192 1e-0.145t,T1/2=4.8 d,C=1.604e-0.231t,T1/2=3.0 d,C=3.132 9e-0.156 4t,T1/2=4.4 dunder 25 ℃ with 20%,40%,60%humidity individually.C=2.304 1e-0.146 3t,T1/2=4.7 d;C=1.604e-0.231t,T1/2=3.0 d;C=0.702 9e-0.231 4t,T1/2=2.9 d under 20,25,30 ℃ with 40% humidity.Conclusion]The fastest degradation rate of acetamiprid was 30 ℃ with 40% humidity.
Keywords:Acetamiprid  Degradation  Brown soil  
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