| 苦皮滕素Ⅴ在土壤中的消解动态及降解产物 |
| |
| 引用本文： | 刘伟,姬志勤,吴文君,魏少鹏.苦皮滕素Ⅴ在土壤中的消解动态及降解产物[J].农药学学报,2015,17(2):241-245. |
| |
| 作者姓名： | 刘伟 姬志勤 吴文君 魏少鹏 |
| |
| 作者单位： | 1.西北农林科技大学 植物保护学院, 陕西 杨凌 712100 |
| |
| 基金项目： | 国家自然科学基金(31371973,31301700);陕西省自然科学基金(2013JQ3003);中央高校基本科研业务费专项(QN2013009). |
| |
| 摘 要： | 为指导苦皮藤素制剂的科学合理使用,采用高效液相色谱-电喷雾多级串联质谱技术(HPLC-ESI-MS/MS)研究了苦皮藤素V在4种土壤中的消解动态及其降解产物。结果表明:苦皮藤素V在江西红土和陕西黄土中消解缓慢,90 d的消解率仅为68.0%和65.0%;在黑龙江黑土和天津碱土中消解相对较快,90 d时消解率分别为84.9%和95.1%。苦皮藤素V在4种土壤中的主要降解产物为一系列在其C-1、C-2和C-8位发生酯键水解而形成的3-羟基、4-羟基及5-羟基的二氢沉香呋喃多元酯。
|
| 关 键 词： | 苦皮藤素V 消解动态 降解产物 土壤 |
| 收稿时间： | 2014/10/28 0:00:00 |
Decline dynamics and degradation products of celangulin V in soils |
| |
| Liu Wei,Ji Zhiqin,Wu Wenjun and Wei Shaopeng.Decline dynamics and degradation products of celangulin V in soils[J].Chinese Journal of Pesticide Science,2015,17(2):241-245. |
| |
| Authors: | Liu Wei Ji Zhiqin Wu Wenjun and Wei Shaopeng |
| |
| Institution: | 1.College of Plant Protection, Northwest A& F University, Yangling 712100, Shaanxi Province, China2.Institute for the Control of Agrochemicals, Xi'an 710003, China |
| |
| Abstract: | For rational and scientific use of celangulin formulation, the decline dynamics and degradation products of celangulin V in four soils were studied by HPLC-ESI-MS/MS. The decline rates of celangulin V were 68.0% and 65.0% at 90 d in Jiangxi laterite and Shaanxi loess. In Heilongjiang black soil and Tianjin alkaline soil, decline rates were 84.9% and 95.1%, respectively. The degradation products of celanlulin V were also investigated by HPLC-ESI-MS/MS. The result showed that the main degradation products were from the break of varies ester bonds substituted at C-1, C-2 and C-8 of the β-dihydroagrofuran sesquiterpene skeleton.The structures of three metabolite compounds were deduced by their MS/MS spectrum. |
| |
| Keywords: | celangulin V decline dynamics degradation products soil |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《农药学学报》浏览原始摘要信息 |
| 点击此处可从《农药学学报》下载免费的PDF全文 |
|
