养殖水体中氯酚残留特征及其与环境因子关系初探 |
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引用本文: | 董军,;陈若虹,;梁锐杰.养殖水体中氯酚残留特征及其与环境因子关系初探[J].农业环境保护,2009(3):602-605. |
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作者姓名: | 董军 ;陈若虹 ;梁锐杰 |
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作者单位: | [1]中山大学生命科学学院,广东广州510275; [2]中山学院化学与生物系,广东中山528403 |
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基金项目: | 广东省自然科学基金项目(7010723);中山市科技计划项目(2006A154);中山学院科研启动项目(2007YKQ19) |
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摘 要: | 采用固相微萃取(SPME)与气-质联用方法,测定分析了3种养殖模式水体中氯酚化合物(CPs)的污染特征。结果表明,19种CPs类化合物在一般四大家鱼养殖水体(A)、猪-鱼综合养殖模式水体(B)以及鸭-鱼综合养殖模式水体(C)表层水中的分布特征相似。总CPs及10种CPs化合物在不同养殖方式水体中浓度由高到低的顺序为A〉B〉C。表层水中残留浓度比较高的一氯酚、二氯酚、三氯酚和四氯酚分别是3-CP和4-CP、2,4-DCP、2,4,6-TCP、2,3,4,6-TCP。回归分析表明,铁、锰总含量与总CPs和PCP含量存在显著负相关。
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关 键 词: | 养殖水 氯酚 残留 环境因子 |
The Dependence of Residues of Chlorophenols in Aquiculture Surface Water on Aquatic Environmental Conditions |
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Institution: | DONG Jun, CHEN Ruo-hong, LIANG Rui-jie (1.School of Life Science, Sun Yatsen University, Guangzhou 510275, China; 2.Department of Chemistry and Biology, Zhongshan College, Zhongshan 528403, China ) |
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Abstract: | Content levels of 19 kinds of chlorophenols (CPs)in aquicuhure surface water were determined by means of solid phase microextraction( SPME )and gas chromatography-mass spectra( GC-MS ). The investigated aquaculture models included traditional feeding( A ), pigfish compound aquaculture( B )and duck-fish compound aquacuhure( C ). The results showed that the distribution of 19 kinds of chlorophenols( CPs )in three kinds of aquicuhure surface water presented at a similar way. The content of total CPs and total content of 10 kinds of CPs chemicals in fishponds from high to low were ranked as the order of A 〉 B 〉 C. The concentrations of 2,4-DCP, 2,4,6-TCP and 2,3,4,6-TCP had a higher level. There should be a significant negative relationship between the contents of total CPs and PCP and the contents of total-Fe and Total-Mn. |
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Keywords: | aquicuhure surface water chlorophenols residue environmental conditions |
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