颗粒活性炭对4-氯酚模拟废水吸附研究 |
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引用本文: | 吴志斌,李媚,廖安平.颗粒活性炭对4-氯酚模拟废水吸附研究[J].安徽农业科学,2010,38(24):13343-13344,13354. |
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作者姓名: | 吴志斌 李媚 廖安平 |
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作者单位: | 1. 广西大学化学化工学院,广西南宁,530004 2. 广西大学化学化工学院,广西南宁,530004;广西民族大学化学与生态工程学院,化学与生物转化过程新技术广西高校重点实验室,广西南宁,530006 3. 广西民族大学化学与生态工程学院,化学与生物转化过程新技术广西高校重点实验室,广西南宁,530006 |
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基金项目: | 广西科学基金项目,广西科学研究与技术开发计划项目,广西教育厅项目 |
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摘 要: | 目的]将颗粒活性炭应用于吸附处理含4-氯酚废水。方法]研究颗粒活性炭对模拟废水中4-氯酚的吸附过程。结果]在30℃,摇床转速为150r/min时,颗粒活性炭对4-氯酚静态吸附6h可达吸附平衡;采用Langemuir和Freundlich吸附等温式对试验数据进行线性拟合,4-氯酚在颗粒活性炭上的吸附行为符合Freundlich等温式。测定了30℃时4-氯酚通过颗粒活性炭固定床的穿透曲线,穿透时颗粒活性炭的吸附容量为37.8mg/g,为同条件下静态吸附容量的0.5018。结论]颗粒活性炭对模拟废水中的4-氯酚具有良好的吸附作用。
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关 键 词: | 颗粒活性炭 4-氯酚 等温吸附 穿透曲线 |
Study on Adsorption of the Granular Activated Carbon on Simulated Wastewater with 4-chlorophenol |
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Institution: | WU Zhi-bin et al (School of Chemistry and Chemical Engineering of Guangxi University , Nanning, Guangxi 530004) |
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Abstract: | Objective ] The aim of the study was to use GAC ( Granular activated carbon) for adsorption treatment of wastewate containing 4- chlorophenol. Method ] The adsorption process of 4-chlorophenol in simulated wastewater by GAC was studied. Result ] Under 30℃ and the 150r/min of shaker speed, the time of the granular activated carbon on 4-chlorophenol adsorption equilibrium was 6 hours. The experimental data was regressed by langemuir and freundlich isotherm models . The adsorption behavior of granular activated carbon on 4-chlorophenol conformed to freundlich isotherm equation. The breakthrough curve of 4-chlorophenol through granular activated carbon fixed bed was measured at 30 ℃. The results showed that the granular activated carbon adsorption capacity at the penetration point was 37.8 mg/g carbon, only 0. 501 8 of the static adsorption capacity at the same conditions. Conclusion ] The GAC had very good performance in absorption of simulated wastewater with 4-chlorophenol. |
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Keywords: | Granular activated carbon 4-chlorophenol Adsorption isotherm Penetration curve |
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