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Probing of an environmentally friendly regenerated cellulose material having bimorphic behavior
Authors:Woo Sub Shim  Jae Pil Kim  Jung Jin Lee  Joonseok Koh  Ik Soo Kim
Institution:(1) Department of Materials Science and Engineering, Seoul National University, Seoul, 151-742, Korea;(2) Fiber System Engineering Program, Division of Polymer System Engineering, Dankook University, Yongin, 448-701, Korea;(3) Department of Textile Engineering, Konkuk University, Seoul, 143-701, Korea;(4) SK Chemicals, Gyeonggi-do, 440-745, Korea;(5) Textile Engineering, Chemistry & Science Department, North Carolina State University, Raleigh, NC 27695-8301, USA
Abstract:Novel regenerated cellulose material which was prepared from cellulose acetate fiber through the hydrolysis of acetyl groups have been developed by an environmentally friendly process without emitting toxic substances in addition to be at low production cost. They have composite crystalline structure constituted of cellulose II and cellulose IV. Also, they show a lamellar morphology with an increased amorphous region, as compared to conventional regenerated cellulose such as viscose rayon and cupra rayon. Our data obtained by several independent methods demonstrated that the adsorption properties of cellulose fibers depend predominantly on the amorphous region.
Keywords:Regenerated cellulose  Crystalline structure  Amorphous region  Viscose rayon  Cuprammonium rayon
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