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Special features of humus acids extraction from soils by sodium pyrophosphate solutions of different alkalinity
Authors:L. G. Bakina  N. E. Orlova
Affiliation:1.St. Petersburg Research Center of Ecological Safety,St. Petersburg,Russia;2.St. Petersburg State University,St. Petersburg,Russia
Abstract:The regularities of extracting humus acids from soils of different types with solutions of sodium pyrophosphate at the equilibrium pH values of 5–13 were studied. The increase in the humus acids yield from the soils with the increasing alkalinity of the solution applied is directly related to the capability of acid functional groups (carboxyl and phenol hydroxyl) for dissociation at definite pH values. The regularities of the changes in the chemical nature and degree of humification of humus acids extracted from the soils related to the pH of the solution were revealed. A sodium pyrophosphate solution (pH 10) was suggested for extracting the humus acids most active in the given soil.
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