| 三聚氰胺甲醛树脂-钯络合物催化剂的表征及催化活性 |
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| 引用本文： | 齐传民,张振权,孙云鸿. 三聚氰胺甲醛树脂-钯络合物催化剂的表征及催化活性[J]. 中国农业大学学报, 1995, 0(Z1): 47-51 |
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| 作者姓名： | 齐传民 张振权 孙云鸿 |
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| 作者单位： | 北京农业大学应用化学研究所;东北师范大学化学系;东北师范大学化学系 北京; |
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| 摘 要： | 报道了三聚氰胺甲醛树脂-Pd催化剂的表征。通过光电子能谱、电子探针、顺磁共振谱、X-射线衍射等测试结果证明新催化剂是载体与Pd(Ⅰ)络合,起催化作用的是零价钯。三聚氰胺甲醛树脂的聚和度不同其对硝基化合物的活性、选择性不同。该催化剂对蓖麻油有较强的催化氢化能力,其氢化蓖麻油的碘值可以达到3,对其他油也有较好的活性。
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| 关 键 词： | 钯 催化剂 催化氢化 三聚氰胺甲醛树脂 |
The Demonstration and Catalytic Hydrogenation of Melamine Formaldehyde Resin-Pd Complex Catalyst |
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| Qi Chuanmin (Institute of Applied Chemistry,BAU,Beijing ,Zhang Zhenquan Sun Yunhong (Dept.of Chemistry,Northeast Normal University. The Demonstration and Catalytic Hydrogenation of Melamine Formaldehyde Resin-Pd Complex Catalyst[J]. Journal of China Agricultural University, 1995, 0(Z1): 47-51 |
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| Authors: | Qi Chuanmin (Institute of Applied Chemistry BAU Beijing Zhang Zhenquan Sun Yunhong (Dept.of Chemistry Northeast Normal University |
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| Affiliation: | Qi Chuanmin (Institute of Applied Chemistry,BAU,Beijing 100094),Zhang Zhenquan Sun Yunhong (Dept.of Chemistry,Northeast Normal University) |
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| Abstract: | Melamine formaldehyde resin-Pd complex as hydrogenation catalyst has been studied by XPS,FT--IR,EPMA XRD and ESR.The results measured showed that the coordinate bonds were formed between the palladium atoms and the C=N- or -N= groups in the catalyst.The results also tell that the oxidation stats of the palladium were 2+(Pd~(2+)) in the fresh catalyst and 0 (Pd~0) in the used cata- lyst.The influence of temperature and the N/Pd atomic ratio in the catalyst on the rate of hydrogenation absorption was measured... |
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| Keywords: | palladium catalyst catalytic hydrogenation melamine formaldehyde resin |
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