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Ferrous ions accelerate sulfide-induced abiotic dechlorination of DDT in waterlogged paddy soil and in soil solution
Authors:Yu-Xin Ba  Zheng-Yi Hu  Peng Bao  Min Qiao  Jing Hua  Chun-Yan Wu  Jian-Zhi Wu
Institution:(1) College of Resources and Environment, Graduate University of Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China;(2) Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, People’s Republic of China;(3) Institute of environmental resources and soil fertilizer, Zhejiang academy of agricultural Sciences, Hangzhou, 310021, People’s Republic of China;
Abstract:

Purpose  

Abiotic dechlorination of organochlorine pollutants seems to occur more efficiently in nature than previously thought. Ferrous (Fe2+) and sulfide (S2−) ions have been shown to be effective dechlorinating reagents. However, little is known about the interactions between Fe2+ and S2− during dechlorination of 1,1,1-trichoro-2,2-bis(p-chlorophenyl)-ethane (DDT) in soil, in spite of the fact that these ions co-exist in waterlogged soils.
Keywords:
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