Polycyclic Aromatic Hydrocarbon Oxidation from Concentrates Issued from an Attrition Process of Polluted Soil Using the Fenton Reagent and Permanganate |
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Authors: | Malika Bendouz Justine Dionne Lan Huong Tran Lucie Coudert Guy Mercier Jean-François Blais |
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Affiliation: | 1.Institut national de la recherche scientifique (Centre Eau, Terre et Environnement),Université du Québec,Québec,Canada |
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Abstract: | This study was conducted to determine the optimal conditions for PAH degradation from highly contaminated attrition sludge (PAC) using a Fenton process or successive permanganate (KMnO4) oxidation and Fenton processes. The following parameters were studied to optimize the Fenton oxidation process: the amounts of reactants based on the stoichiometric oxidant demand (SOD), the reactant addition protocol and number of doses, and the solid/liquid ratio (S/L). The results showed that the following conditions were optimum: TS?=?30%, 7.5 times SOD, H2O2/Fe2+ ratio?=?10, and added five times during 60 min, which allowed the degradation of 43% of total 27 PAHs from the PAC. Successive Fenton and KMnO4 oxidation processes were also tested. PAH degradation using a sequential Fenton process followed by KMnO4 oxidation (or KMnO4 followed by Fenton) was higher than for the use of Fenton or KMnO4 treatment alone. Up to 71% of the total 27 PAHs were degraded when using a combination of both processes. It appeared that the sequential treatment is a viable method for the significant degradation of 27 PAHs from PAC (t value?>?2.77). |
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