自形成MnFe2O4磁性液体的制备和磁性

用化学共沉淀法制备MnFe2O4纳米微粒,并且采用自形成法制备了粒子型磁性液体.在这种磁性液体中,通过适当的酸蚀,Mn2+和Fe3+离子从MnFe2O4纳米微粒溶解并吸附在磁性微粒表面以阻止微粒团聚.微粒和磁性液体都呈磁滞回线.这种磁化性质可能来源于在高场下产生的不可逆团聚.

Abstract：

MnFe2O4 nanoparticles are prepared by chemical coprecipitation method. Based on the MnFe2O4 nanoparticles, a self-formed ionic ferrofluid is synthesized. In the ferrofluid, Mn2+ and Fe3+ ions dissolved from the MnFe2O4 nanoparticles via suitable acid attack are adsorbed on the surface of the magnetic particles, thus preventing the particles from aggregating. The average thickness of ionized layers of the ferrofluid particles is about 1 to 2 nm.Both the particles and the ferrofluids have hysteresis behavior. The behavior may result from irreversible aggregation induced under high magnetic field.     

ZnFe2O4基磁凝胶的制备及磁性

用自形成法制备ZnFe2O4磁凝胶,并进一步研究包裹ZnFe2O4的γ-Fe2O3磁凝胶的制备,用振动样品磁强计(VSM)对ZnFe2O4和包裹ZnFe2O4的γ-Fe2O3磁性微粒及配制的胶体处在溶胶和凝胶的磁性测量.结果表明ZnFe2O4磁性微粒和胶体呈顺磁性,而包裹ZnFe2O4的γ-Fe2O3磁性微粒和胶体呈亚铁磁性.ZnFe2O4凝胶较其溶胶易磁化,而ZnFe2O4/γ-Fe2O3凝胶较其溶胶难磁化.从微观机制上解释了产生这些磁性差异的原因.

Abstract：

ZnFe2O4 magnetic gel is prepared by the self-formed method, and the preparation of γ-Fe2O3 coated with ZnFe2O4 is studied. The magnetization of ZnFe2O4 and γ-Fe2O3 nanoparticles coated with ZnFe2O4 and their gels and sols are measured by a vibrating sample magnetometer(VSM). The results show that the ZnFe2O4 powder and its colloid are paramagnetic, while the γ-Fe2O3 magnetic particles coated with ZnFe2O4 and colloid show ferrimagnetism. ZnFe2O4 gel is easier to be magnetized than sol. However, ZnFe2O4/γ-Fe2O3 gel is harder magnetized than sol. The reason for the difference in magnetization is interpreted microscopically.     

COFe2O4-p-NiFe2O4二元离子型磁性液体的制备及其场致光透射驰豫

介绍了CoFe2O4-p-NiF2O4二元离子型磁性液体的制备方法,用X射线衍射仪、透射电子显微镜、振动样品磁强计分别对NiFe2O4微粒前驱体(p.NiFe2O4)和COFe2O4微粒的结构、粒径和磁性进行了测量与分析,研究了CoFe2O4-p-NiFe2O4二元离子型磁性液体在平行于激光照射方向具有不同梯度的外磁场作用下的场致透光的驰豫时间,并从微观结构上分析了产生驰豫时间差异的原因.     

自形成法γ-Fe2O3磁性液体的制备及磁性

介绍了自形成法γ-Fe2O3磁性液体的制备方法,用X射线衍射仪（XRD〉和透射电子显微镜（TEM）对微粒进行了表征,并用振动样品磁强计（VSM）对γ-Fe2O3粉末及水基γ-Fe2O3离子型磁性液体进行了测量．结果表明：γ-Fe2O3粉末及其磁性液体呈超顺磁性,在室温下无矫顽力和剩磁;磁性液体的比饱和磁化强度与磁性液体中微粒的体积分数以及基液的磁性有关;在磁性液体的合成中,强磁性的γ-Fe2O3微粒可能形成磁矩闭合连接成环状结构,以致磁性液体的比饱和磁化强度的实验值小于计算值．     

COFe2O4-p-NiFe2O4二元离子型磁性液体的制备及其场致光透射驰豫

介绍了CoFe2O4-p-NiFe2O4二元离子型磁性液体的制备方法,用X射线衍射仪、透射电子显微镜、振动样品磁强计分别对NiFe2O4微粒前驱体（p-NiFe2O4）和CoFez04微粒的结构、粒径和磁性进行了测量与分析。研究了CoFe2O4-p-NiFe2O4二元离子型磁性液体在平行于激光照射方向具有不同梯度的外磁场作用下的场致透光的驰豫时间,并从微观结构上分析了产生驰豫时间差异的原因。     

二元CoFe2O4-p-MgFe2O4磁性液体的制备及磁化特性研究

采用化学共沉淀法制备了CoFe2O4强磁性纳米微粒和p-MgFe2O4(Mg(OH)2与Fe(OH)3的混合物)弱磁性纳米微粒.并按体积比为1:1将CoFe2O4磁性液体、p-MgFe2O4顺磁磁性液体混合,得到二元CoFe2O4-p-Mg-Fe2O4磁性液体.实验结果表明混合磁性液体的磁化强度不能简单等于两种单一磁性液体磁化强度的叠加.在CoFe2O4磁性液体中,其磁性微粒在无场时会自发组装形成对磁化强度无贡献的闭合环状团聚体结构.二元磁性液体磁化时,这种CoFe2O4微粒环可能部分破裂.根据偶极子相互作用能判断CoFe2O4体系与p-MgFe2O4体系无相互作用,因此可根据单元磁性液体的磁化性质为基础来分析二元磁性液体的磁化性质.

Abstract：

Strong magnetic CoFe2O4 nanoparticles and weak magnetic p-MgFe2O4 (mixture of hydroxide Mg(OH)2 and Fe(OH)3) nanoparticles are produced by the chemical co-precipitation technology. Binary ferrofluids of CoFe2O4-p-MgFe2O4 are obtained by mixing CoFe2O4 ferrofluids and p-MgFe2O4 paramagnetic fluids in a ratio of 1: 1 (v/v). The experimental results indicate that the magnetization of the binary ferrofluid is not simple summation of the two single magnetic fluids. Without external magnetic field,some particles can self-assemble into aggregates of closed ring-like structures, which make no contribution to the magnetization for the CoFe2O4 ferofluid. In the magnetization process of the binary ferrofluid, the closed ring-like structure can partially break. Based on the interaction between two dipoles, it can be judged that there is no magnetic interaction between the CoFe2O4 magnetic system and the p-MgFe2O4 magnetic system. Therefore, the magnetization behavior of the binary ferrofluids can be analyzed based on the single magnetic fluids.     

CuFe2O4离子型磁性液体的场致光透射性质研究

研究了Massart法制备的CuFe2O4离子型磁性液体在磁场作用下,光透射率随时间的变化规律,光透射率的变化与磁性液体的体积分数、磁场大小、光路及磁场方向有关,为解释光透射率变化的原因,建立了在磁场作用下,磁性液体纳米微粒形成链,并在磁场梯度作用下微粒链向中心会聚,而并列链问的排斥力又使链发散的链振荡运动的微观模型。     

CuFe2O4离子型磁性液体的场致光透射性质研究

研究了Massart法制备的CuFe2O4离子型磁性液体在磁场作用下, 光透射率随时间的变化规律. 光透射率的变化与磁性液体的体积分数、磁场大小、光路及磁场方向有关. 为解释光透射率变化的原因, 建立了在磁场作用下, 磁性液体纳米微粒形成链, 并在磁场梯度作用下微粒链向中心会聚, 而并列链间的排斥力又使链发散的链振荡运动的微观模型.     

自形成法γ-Fe2O3磁性液体的制备及磁性

介绍了自形成法γ-Fe2O3磁性液体的制备方法, 用X射线衍射仪(XRD)和透射电子显微镜(TEM)对微粒进行了表征, 并用振动样品磁强计(VSM)对γ-Fe2O3粉末及水基γ-Fe2O3离子型磁性液体进行了测量. 结果表明: γ-Fe2O3粉末及其磁性液体呈超顺磁性, 在室温下无矫顽力和剩磁;磁性液体的比饱和磁化强度与磁性液体中微粒的体积分数以及基液的磁性有关;在磁性液体的合成中, 强磁性的γ-Fe2O3微粒可能形成磁矩闭合连接成环状结构, 以致磁性液体的比饱和磁化强度的实验值小于计算值.